钻井液降滤失剂PAAS的制备及其性能、机理研究
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Synthesis, Performanceand Mechanism Research of Drilling Fluid Filtrate Reducer PAAS
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    摘要:

    以2-丙烯酰胺基-2-甲基丙磺酸(AMPS)、丙烯酰胺(AM)和对苯乙烯磺酸钠(SSS)为聚合单体采用反相乳液聚合法制备了一种新型水基钻井液降滤失剂PAAS,通过正交实验法确定了其最佳合成条件,采用红外光谱及元素分析对其结构进行了表征,实验表明共聚物PAAS分子结构满足预期设计;此外,热综合分析显示共聚物PAAS具备良好的高温稳定性。钻井液流变性实验、老化实验及失水实验表明:降滤失剂质量加量为1.5%时,钻井液流变性良好,高温160 ℃老化前后失水量分别为FLAPI=8.4 mL和FLAPI=10.2 mL;吸附实验、滤饼微观结构和横向弛豫时间T2表明该降滤失剂PAAS主要通过吸附作用改善钻井液体系滤失性能。

    Abstract:

    In this paper, a new kind of filtrate reducer PAAS is prepared with 2-acrylamide-2-methylpro panesulfonic acid (AMPS), acrylamide (AM) and sodium p-styrene sulfonate (SSS) by inverse emulsion polymerization, and the optimal synthesis conditions is obtained through orthogonal experiment. And the molecular structure is confirmed by FT-IR and element analysis, which shows that the molecular structure of PAAS meet the expected design structure. And then the comprehensive thermal analysis shows that the polymer PAAS have a good thermal stability. In addition, the rheological experiments, high temperature aging experiments and fluid loss experiment shows that the drilling fluid have a good rheological properties when the adding amount of polymer PAAS is 1.5 wt%, and the FLAPI=8.4 mL before aging under 160 ℃, and the FLAPI=10.2 mL after aging. Finally, the adsorption experiment, micro structure and transverse relaxation time of filter cake shows that the filtrate reducer reduce fluid loss by adsorption.

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张瑞,霍锦华,彭志刚.钻井液降滤失剂PAAS的制备及其性能、机理研究[J].精细化工,2017,34(5):0

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  • 收稿日期:2016-08-29
  • 最后修改日期:2016-12-05
  • 录用日期:2017-01-09
  • 在线发布日期: 2017-04-07
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