α-纤维素/魔芋葡甘聚糖复合水凝胶的制备及其性能
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TQ314

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国家自然科学基金项目(面上项目,重点项目,重大项目)


Preparation and Properties of α-Cellulose/Konjac Glucomannan Composite Hydrogels
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The National Natural Science Foundation of China (General Program, Key Program, Major Research Plan)

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    摘要:

    为提高魔芋葡甘聚糖(Konjac glucomannan,KGM)凝胶的热稳定性和凝胶强度,通过与α-纤维素(α-Cellulose,α-CE)按不同比例复配制得α-CE/KGM复合水凝胶。使用旋转流变仪测定加入不同量α-CE对复合水凝胶流变特性的影响,利用扫描电子显微镜(SEM)、红外光谱(FTIR)和差式扫描量热计(DSC)表征α-CE/KGM水凝胶的表观形貌、微观结构、特征官能团及其热稳定性。结果显示,KGM溶胶和α-CE/KGM溶胶的黏度随剪切速率的增大而减小;在0~300s-1剪切速率内,剪切应力随剪切速率的增大而增大;在0.1~100 Hz频率内,α-CE/KGM的储能模量(G’)低于其损耗模量(G”),α-CE的添加使复合水凝胶的模量升高。在不同质量比的α-CE/KGM凝胶体系中,当m(α-CE):m(KGM)=1:1(即α-CE4)时得到的复合水凝胶,熔融吸收峰为122.3℃,热稳定性高有所提高

    Abstract:

    α-CE/KGM composite hydrogels were prepared by mixing konjac glucomannan (KGM) and α-cellulose (α-CE) in different proportions to improve the thermal stability and gel strength of KGM hydrogels. We used the Rotational Rheometer to research the influence of different quantities of α-CE on the rheological properties of the KGM gels.The surface morphology, characteristic functional groups, thermal stability and microstructure of α-CE/KGM hydrogels were characterized by scanning electron microscope (SEM), infrared spectroscopy (FT-IR) and differential scanning calorimetry (DSC). Result reveals that the viscosity of KGM sol and α-CE / KGM sol decreases with the increase of shear rate. In the range of 0 to 300s-1, the shear stress increases with the increase of shear rate. At the selected frequency in the range of 0.1 to 100 Hz, the storage modulus G' of α-CE / KGM is lower than its loss modulus G'', and the addition of α-CE increases the modulus. Especially when m(α-CE):m(KGM)=1:1 (α-CE4), the melting absorption peak is 122.3℃, and the thermal stability is improved.

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刘子奇,王林,王维海,杨金初,吴先辉,庞杰.α-纤维素/魔芋葡甘聚糖复合水凝胶的制备及其性能[J].精细化工,2018,35(7):

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  • 收稿日期:2017-07-24
  • 最后修改日期:2017-12-15
  • 录用日期:2018-01-12
  • 在线发布日期: 2018-06-11
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