压裂用疏水缔合聚合物溶液性质及减阻性能研究
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TE357.12

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Study of Solution Properties and Drag Reduction of Hydrophobically Associating Polymer for Fracturing Fluids
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    摘要:

    摘要:以一种功能性疏水单体与丙烯酰胺(AM)、丙烯酸(AA)和2-丙烯酰胺-2-甲基丙磺酸(AMPS)为原料,合成了一种疏水缔合聚合物HAWP-18。采用流变仪考察了疏水缔合聚合物HAWP-18的耐剪切性能、黏弹性及触变性,结果表明,HAWP-18属于假塑性流体,临界缔合浓度为2.31g/L,表现出较强的耐剪切性能;黏弹性测试表明,HAWP-18是典型的黏弹性结构流体,具有较宽的线性黏弹区,该体系的储能模量G'大于损耗模量G'',并且黏度越大,弹性特征越强;采用稳态剪切测试研究了不同质量浓度HAWP-18的剪切应力与剪切速率的关系,HAWP-18具有触变性,并且触变性随质量浓度增大而增强;使用自制摩阻测试仪测定了不同质量浓度HAWP-1的减阻性能,结果表明,HAWP-18减阻率随质量浓度的增加先上升后降低。HAWP-18的耐剪切性及其良好的黏弹性、触变性和减阻性能为其应用于压裂液提供了实验支撑。

    Abstract:

    Abstract:A hydrophobically associating polymer HAWP-18 was synthesized by using a functional hydrophobic monomer, acrylamide (AM), acrylic acid (AA) and 2-Acrylamido-2-methylpropane sulfonic acid (AMPS) as raw materials. Properties of shearing resistance, viscoelasticity and thixotropy of hydrophobic associating polymer HAWP-18 was investigated by using rheometer. The results show that HAWP-18 solutions were pseudoplastic fluid and exhibited stronger shearing resistance, and the critical associating concentration of HAWP-18 solution was 2.31g/L. According to the viscoelasticity results, HAWP-18 is a typical viscoelastic structure fluid and has a relatively wide linear viscoelastic region. The value of storage modulus (G') is larger than loss modulus (G''). The higher the viscosity was, the stronger the elastic characteristic of HAWP-18 was. The variation of shear stress with shear rate was also discussed by using steady-state shear test of HAWP-18 with different mass concentrations. It was shown that HAWP-18 had thixotropy property. With the increment of the mass concentration, the thixotropy property enhanced. The drag reduction property of HAWP-18 solutions with different mass concentrations was tested by using homemade friction tester. The drag reduction test showed that the drag reduction rate of HAWP-18 increased at first and decreased latter with the increment of the HAWP-18. The shearing resistance, good viscoelasticity, thixotropy, and drag reduction of HAWP-18 provide experimental support for its application in fracturing fluids.

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马国艳,沈一丁,王小荣,郭兴,赵倩云.压裂用疏水缔合聚合物溶液性质及减阻性能研究[J].精细化工,2016,33(10):0

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历史
  • 收稿日期:2016-03-28
  • 最后修改日期:2016-05-19
  • 录用日期:2016-06-21
  • 在线发布日期: 2016-09-13
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