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第 35 卷第 10 期 精 细 化 工 Vol.35, No.10
2018 年 10 月 FINE CHEMICALS Oct. 2018
综论
耐温表面活性剂在油藏开发中的研究进展
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潘 一 ,赵 旭 ,杨双春 ,Ongarbayev Asset ,米俊锋 ,张海燕
(1. 辽宁石油化工大学 石油天然气工程学院 辽宁 抚顺 113001;2. 钦州学院 石油与化工学院 广西高
校北部湾石油天然气资源有效利用重点实验室,广西 钦州 535011)
摘要:表面活性剂驱是三次采油中稳产增产的重要手段,随着高温油藏研究开发的不断深入,耐高温表面活性
剂具有更加重要的研究价值。该文根据深层油藏温度高的特点和中国油藏开发现状,在研究国内外文献资料的
基础上,将具有耐高温性能的表面活性剂按阴-非离子型(Anionic-nonionic)、两性型(Amphoteric)、双子型
(Gemini)和氟碳型(Fluorocarbon)分类。通过对 4 类表面活性剂的比较,讨论了基团、分子结构等因素对
表面活性剂耐温性的影响,指出可生物降解表面活性剂是耐温表面活性剂继续发展的重要方向,同时对双子表
面活性剂的合成及氟碳表面活性剂的应用提出了建议。
关键词:高温;表面活性剂;表面张力;稳定性
中图分类号:TE3 文献标识码:A 文章编号:1003-5214 (2018) 10-1621-09
Research Progress on Surfactants for High Temperature Reservoirs
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PAN Yi , ZHAO Xu , YANG Shuang-chun , Ongarbayev Asset ,
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MI Jun-feng , ZHANG Hai-yan
(1. College of Petroleum and Natural Gas Engineering, Liaoning Shihua University, Fushun 113001, Liaoning, China; 2.
Key Laboratory of Effective Utilization of Oil and Gas Resources in Beibu Gulf of Guangxi University, College of Petroleum
and Chemical Engineering, Qinzhou University, Qinzhou 535011, Guangxi, China)
Abstract: Surfactant flooding used in tertiary oil recovery is a kind of crucial method for stable oil
production and increasing oil production. Along with the continuing research and exploitation of high-
temperature reservoir, high-temperature resistant surfactants have more important research value.
According to the characteristics of high-temperature reservoir and its development status in China, high-
temperature resistant surfactants can be divided into four categories: anionic-nonionic, amphoteric, Gemini
and fluorocarbon surfactants. By comparing the surfactants reviewed in this paper, some factors affecting
their temperature resistance such as group and molecular structure are discussed. Subsequently, it is also
pointed out that the biodegradable surfactant is one of the most important research directions of high-
temperature resistant surfactants. At the same time, some suggestions on the synthesis of Gemini
surfactants and the application of fluorocarbon surfactants are put forward.
Key words: high temperature; surfactants; surface tension; stability
Foundation items: Petro China Science and Technology Innovation Foundation(2107D-5007-0201);
Opening Project of Guangxi Colleges and Universities Key Laboratory of Beibu Gulf Oil and Natural Gas
Resource Effective Utilization (2016KLOG03)
[1]
石油是当今世界最重要的战略能源,各国对石 大型高温油气田数目却以较快速度增长 。目前,
油都非常重视。传统石油理论认为温度过高的地层 常规油藏勘探开发已经进入后期,而各国对石油的
不具备储集油气的条件,但近年来勘探研究发现的 需求量越来越大,因此,对高温油藏的研究和开发
收稿日期:2017-07-30; 定用日期:2018-03-08; DOI: 10.13550/j.jxhg.20170618
基金项目:2017 年度中国石油科技创新基金项目(2107D-5007-0201);广西高校北部湾石油天然气资源有效利用重点实验室开放课
题(2016KLOG03)
作者简介:潘 一(1976—),男,副教授,E-mail:panyi_bj@126.com。