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第 10 期 陈文娟，等: 驱油用超支化聚合物的合成及性能 ·1757·

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[6] Chen Xirong (陈锡荣), Huang Fengxing (黄凤兴). Research
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[7] Liu X J, Jiang W C, Gou S H. Synthesis and evaluation of a
water-soluble acrylamide binary sulfonates copolymer on MMT
crystalline interspace and EOR[J]. Journal of Applied Polymer
Scienc, 2012, 125(2): 1252-1260．

图 10 HPAM 及 HCD-HPAM-BTAM 聚合物的抗盐性能 [8] Zhang Qin (张勤), Gou Shaohua (苟绍华), Li Shiwei (李世伟), et al.
Fig. 10 Salt resistance of polymers HPAM and HCD- Synthesis and poperties of arylamide-based cpolymer cntaining
HPAM-BTAM pridine unit[J]. Fine Chemicals (精细化工), 2017, 34(1): 102-108.
[9] Qin Xiaoping (覃孝平), Ye Zhongbin (叶仲斌), Lai Nanjun (赖南

君 ). Synthesis and performance of a water-soluble AM-AA-
3 结论 NVP-DAMA tetra-copolymer for enhanced oil recovery[J]. Fine
Chemicals (精细化工), 2013, 30(12): 1423-1440.
设计合成了一种具备三维立体球形结构及两性 [10] Xu Junqi (徐骏祺), Huang Tong (黄通), Lv Xin (吕鑫), et al.
离子功能链段的超支化聚合物驱油剂 HCD-HPAM- Synthesis and characterization of water-soluble hyperbranched
polyacrylamide with high shear-resistance[J]. Journal of Shanghai
BTAM，主要结论如下： Institute of Technology Natural Science (上海应用技术学院学报
（1）以聚环糊精（HCD）为母核、丙烯酰胺 自然科学版), 2014, 14(4): 277-282.
[11] Liu X J, Jiang W C, Gou S H. Synthsis and evaluation of a
（AM）及甲基丙烯酰乙基磺基甜菜碱（BTAM）为
water-soluble acrylamide binary sulfonates copolymer on MMT
单体，在硝酸铈铵引发下，通过水相自由基聚合， crystalline interspace and EOR[J]. Journal of Applied Polymer
合成了超支化聚合物 HCD-HPAM-BTAM。最佳的 Science, 2012, 125(2): 1252-1260.
[12] Wu Y M, Zhang B Q, Wu T. Properties of the forpolymer of
聚合反应条件为：聚合时间 5.5 h、引发剂 60 mg、 N-vinylpyrrolidone with itaconic acid, acrylamide and
HCD 20~30 mg、烘干温度 120 ℃、BTAM 200 mg。 2-acrylamido-2-methyl-1-propane sulfonic acid as s fluid-loss
reducer for drilling fluid at high temperature[J]. Colloid Polymer
（2）HCD-HPAM-BTAM 具备良好的溶解、增
Science, 2001, 279(9): 836-842.
黏、抗剪切及抗老化性能。在 9374.13 mg/L 的矿化 [13] Yan D Y, Zhou Y F, Hou J. Supramolecular self-assembly of
水中，聚合物基本溶解时间均小于 40 min，2000 mg/L macroscopic tubes[J]. Science, 2004, 303(5654): 65-67.
[14] Mai Y Y, Zhou Y F, Yan D Y. Real-time hierarchical
的聚合物溶液黏度可达到 31.2 mPa·s，Wairing 搅拌 self-assembly of large compound vesicles from an amphiphilic
器 1 档剪切 20 s 后黏度保留率高达 80%，老化 90 d hyperbranched multi-arm-copolymer[J]. Small, 2007, 3(7): 1170-1173.
[15] Jia Z F, Zhou Y F, Yan D Y. Amphiphilic stai-block copolymer based
黏度保留率为 63%，均优于未改性 HPAM 聚合物。
on a hyperbranched core: Sythesis and supramolecular self-
assembly[J]. Jounral of polymer science, 2005, 43(24): 6534-6544.
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