Page 85 - 《精细化工》2020年第12期
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第 37 卷第 12 期                            精   细   化   工                                 Vol.37, No.12
             2020 年 12 月                             FINE CHEMICALS                                 Dec.  2020


              综论
                        循环冷却水系统除碳酸钙污垢的研究进展



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                             赵   彦 ,章立新 ,高   明 ,刘婧楠 ,赵圣仙
                 (1.  上海理工大学  能源与动力工程学院  上海市动力工程多相流动与传热重点实验室,上海  200093;
                 2. 上海安得利给水设备有限公司,上海  200041)
                 摘要:循环冷却水浓缩倍数的提升会加剧换热设备的结垢,同时,工业规模循环冷却水系统的循环冷却水量和
                 排污量也严重制约着阻垢剂和除垢方法的选择。对传统化学阻垢剂、基于石化产品的绿色阻垢剂、基于生物提
                 取物的绿色阻垢剂的特点进行了分析总结,介绍了阻垢剂的研究现状并分析了阻垢剂的发展趋势;简述了常用
                 的物理除垢方法及其研究进展,指出这类方法存在对换热设备的损伤和较低的除垢能力问题;阻垢剂和物理方
                 法组合使用的相关研究表明,物理方法会显著影响阻垢剂的性能。结合循环水系统除垢的研究现状,对除垢的
                 技术发展进行了总结和展望,提出了对阻垢剂和除垢方法使用的建议以及解决相关问题的新思路。
                 关键词:循环冷却水;碳酸钙污垢;阻垢剂;物理除垢方法;组合除垢方法
                 中图分类号:TQ085+.4      文献标识码:A      文章编号:1003-5214 (2020) 12-2447-10


                               Research progress of removing calcium carbonate
                                   fouling in circulating cooling water system


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                          ZHAO Yan , ZHANG Lixin , GAO Ming , LIU Jingnan , ZHAO Shengxian
                 (1. Shanghai  Key Laboratory of Multiphase  Flow and Heat  Transfer  in Power Engineering,  School of Energy and
                 Power Engineering, University of Shanghai for Science and Technology, Shanghai 200093, China; 2. Shanghai Andeli
                 Water Supply Equipment Co., Ltd., Shanghai 200041, China)
                 Abstract: The increase of concentration multiple of circulating cooling water will aggravate the scaling of
                 heat exchange equipment. At the same time, the amount of circulating cooling water and blowdown in the
                 industrial scale circulating cooling water system restrict the selection  of scale inhibitors and  descaling
                 methods. The characteristic of traditional chemical scale inhibitors, green scale inhibitors based on petrochemical
                 products, and green scale inhibitors based on biological extracts are analyzed and summarized. The research
                 status of scale inhibitors is  introduced  and the  development trend of scale inhibitors is analyzed. The
                 common physical descaling  methods and their research  progress are briefly described, which have the
                 problem of  damage to  heat  exchange equipment and lower  descaling  capacity. Some studies show that
                 physical methods can significantly affect the performance of scale inhibitors when scale inhibitors are used
                 in combination  with  physical  methods. Combined  with the current  research situation of  descaling in
                 circulating water system, the development of descaling technology is summarized and prospected, some
                 suggestions on the use of scale inhibitors and descaling methods are put forward, and new ideas for solving
                 related problems are presented.
                 Key words:  circulating cooling  water; calcium carbonate fouling; scale inhibitor; physical  descaling
                 method; combined descaling method


                 工业用水在城市用水中的占比通常可达 50%以                        重要  [2-3] 。在敞开式循环冷却水系统中,循环冷却水
                                                     [1]
            上,其主要作为充当热量交换媒介的冷却水 ,在                             依靠蒸发带走废热因而具有较大的蒸发量,水中溶
                                                                                    2+
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            水资源匮乏的当下,提高冷却水的循环利用率越发                             解的各种矿物离子如 Ca 、Mg 等质量浓度会不断

                 收稿日期:2020-06-27;  定用日期:2020-07-30; DOI: 10.13550/j.jxhg.20200559
                 基金项目:国家自然科学基金(51976127)
                 作者简介:  赵   彦(1995—),男,硕士生,E-mail:usst_zhaoyan@126.com。联系人:章立新(1964—),男,教授,E-mail:uzlx1@126.com。
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