阳离子交换树脂催化合成阿魏酸乙酯
DOI:
CSTR:
作者:
作者单位:

作者简介:

通讯作者:

中图分类号:

基金项目:


Synthesis of Ethyl Ferulate Catalyzed by Strong Acidic Cationic Exchange Resin
Author:
Affiliation:

Fund Project:

  • 摘要
  • |
  • 图/表
  • |
  • 访问统计
  • |
  • 参考文献
  • |
  • 相似文献
  • |
  • 引证文献
  • |
  • 资源附件
  • |
  • 文章评论
    摘要:

    以乙醇和阿魏酸为原料,强酸性阳离子交换树脂为催化剂,直接酯化合成了阿魏酸乙酯,考察了树脂类型、催化剂用量、物质的量比、反应时间、催化剂重复使用性等因素对反应的影响。确定了最佳反应条件为:m(树脂)∶m(阿魏酸)=12%,n(乙醇)∶n(阿魏酸)= 6∶1,加热回流反应时间7 h。在最佳反应条件下,阿魏酸转化率为83.4%,产品收率为78.1%。732型树脂催化剂重复使用4次,阿魏酸转化率不低于81%,收率不低于75%。

    Abstract:

    Ethyl ferulate was synthesized from ethanol and ferulic acid by direct esterification using cation exchange resin as catalyst.The effects of resin type,amount of catalyst,reaction time,materials ratio and repeatability of catalyst on the synthesis were studied.The optimal reaction conditions were given as follows:m(resin)∶m(ferulic acid)=12%,n(ethanol)∶n(ferulic acid)= 6∶1, reflux reaction time 7 h.The yield of product was 83.4% and 78.1% respectively under above conditions. The conversion rate of ferulic acid and yield of product keep greater than 81% and 75% respectively after the 732# resin was used four times.

    参考文献
    相似文献
    引证文献
引用本文

龚盛昭.阳离子交换树脂催化合成阿魏酸乙酯[J].精细化工,2010,27(4):

复制
分享
文章指标
  • 点击次数:
  • 下载次数:
  • HTML阅读次数:
  • 引用次数:
历史
  • 收稿日期:2009-12-04
  • 最后修改日期:2010-01-22
  • 录用日期:2010-01-26
  • 在线发布日期: 2010-04-12
  • 出版日期:
文章二维码