超临界CO2萃取黑胡椒中有效成分的研究
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Comprehensive Extraction of active components from black pepper by Supercritical CO2
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    摘要:

    本文研究利用超临界CO2萃取技术,首先在低压、低温的条件下选择性萃取黑胡椒精油,进而在高温、高压及极性夹带剂的协同作用下,萃取富含胡椒碱的黑胡椒油树脂。另外,利用分子蒸馏技术纯化超临界CO2萃取黑胡椒精油,得到可用于日化行业的无色、无味黑胡椒挥发油,并通过GC-MS对比分析其香气成份。研究结果表明,超临界CO2萃取黑胡椒精油的较优条件为萃取压力10MPa、萃取温度35℃、萃取时间2h,在此条件下产物得率为3.01%,油树脂的最佳萃取条件为m(原料):m(95% 乙醇)=1:1、萃取压力30 MPa、萃取温度50℃、萃取时间4h,在此条件下油树脂得率为7.88%,油树脂中胡椒碱含量≥65%。

    Abstract:

    The supecritical carbon dioxide fluid ectraction(SFE-CO2) of essential oil and oleoresin from black pepper is presented in this study. Firstly, low pressure and temperature was adopted for selective extraction of black pepper essential oil. Then, high pressure and temperature was introduced in the presence of a polar entrainer for black pepper oleoresin riching in piperine. Moreover, black pepper essential oil obtained by supercritical CO2 extraction was purified by molecular distillation into colorless and tasteless product which could be used in the daily chemical industry, aroma components were also analyzed by GC-MS. The experimental results showed that the optimum conditions of supercritical CO2 extraction of black pepper essential oil were 10MPa of pressure, 35℃ of temperature and 2h of time, the yield was 3.01%. The optimum conditions of oleoresin extraction were m(raw material):m(95% ethanol)=1:1, 30MPa of pressure, 50℃ of temperature and 4h of time, the yield was 7.88%, the piperine content in oleoresin exceeded 65%.

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翁少伟.超临界CO2萃取黑胡椒中有效成分的研究[J].精细化工,2010,27(10):

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  • 收稿日期:2010-03-01
  • 最后修改日期:2010-06-21
  • 录用日期:2010-06-29
  • 在线发布日期: 2010-09-07
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