聚丙烯酸/聚丙烯酰胺/凹凸棒复合材料对亚甲基蓝的吸附性能
DOI:
CSTR:
作者:
作者单位:

作者简介:

通讯作者:

中图分类号:

TQ424.2; X788

基金项目:

江苏省科技厅太湖专项 (No. BS2007118);甘肃省科技支撑计划(No. 090NKCG114);甘肃省高校河西走廊特色资源利用省级重点实验室 (No. XZ1010)


Adsorption behaviour of methylene blue onto poly (acrylic acid-co-acrylamide)/attapulgite composite
Author:
Affiliation:

Fund Project:

  • 摘要
  • |
  • 图/表
  • |
  • 访问统计
  • |
  • 参考文献
  • |
  • 相似文献
  • |
  • 引证文献
  • |
  • 资源附件
  • |
  • 文章评论
    摘要:

    将聚丙烯酸/聚丙烯酰胺/凹凸棒复合吸附剂用于亚甲蓝的吸附,研究了时间、浓度、酸度、表面活性剂和离子强度等因素对吸附性能的影响。复合吸附剂对亚甲蓝的吸附是吸热过程,60℃时吸附量达到1273.3 mg•g-1,吸附过程符合Langmuir单分子层吸附等温模式,并计算了热力学常数ΔG、ΔH和ΔS。所有实验参数下吸附过程均符合准二级动力学特征。该复合吸附剂具有高吸附容量和较快的吸附速率,是良好的亚甲蓝吸附剂。

    Abstract:

    Adsorption properties of cationic dye methylene blue (MB) onto poly (acrylic acid-co-acrylamide)/ attapulgite composite clay were investigated. The effects of various experimental parameters such as pH, concentration of the dye, temperature, contact time, adsorbent dosage, ionic strength and surfactant on adsorption process have been studied. Equilibrium isotherms for the adsorption of the dye were measured experimentally. Results were analyzed by Langmiur and Freundlich equation at different temperatures and the characteristic parameters for the adsorption isotherm were determined. The adsorption process has been found endothermic for MB in nature. The thermodynamic parameters such as Gibbs free energy, change in enthalpy and change in entropy have been calculated. The maximum adsorption capacity for MB was obtained as 1273.3 mg g-1 at the temperature of 60℃. It was observed that the kinetic data fitted well with a pseudo second-order equation. The results showed that the composite attapulgite clay could be employed as low-cost alternatives to traditional agent in wastewater treatment for the removal of color.

    参考文献
    相似文献
    引证文献
引用本文

王永生.聚丙烯酸/聚丙烯酰胺/凹凸棒复合材料对亚甲基蓝的吸附性能[J].精细化工,2011,28(2):

复制
分享
文章指标
  • 点击次数:
  • 下载次数:
  • HTML阅读次数:
  • 引用次数:
历史
  • 收稿日期:2010-07-29
  • 最后修改日期:2010-11-04
  • 录用日期:2010-11-05
  • 在线发布日期: 2011-01-10
  • 出版日期:
文章二维码