PAA-AM-AMPS与PAA-AM高吸水性树脂的合成及保水性能
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TQ 325.7; TQ 322.4

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2010年武汉市青年科技晨光计划项目(201050231049);中国海洋石油总公司资助项目(SH-GS-10-ZC-014);绿色化工过程省部共建教育部重点实验室开放基金项目(GCP201003);武汉工程大学科学研究基金(No.10092012)


The Synthesis and Water-retention Property of the PAA-AM-AMPS and PAA-AM Superabsorbent Polymer
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    摘要:

    利用水溶液聚合法合成聚丙烯酸系高吸水性高保水性树脂, 吸水倍率均在800g/g以上, 且在50min内吸水饱和。研究了共聚单体和交联剂用量对加压保水能力和恒温保水能力的影响, 研究结果表明, 树脂恒压放置7d后保水率均在30%以上, 保水能力随丙烯酰胺用量增加先增大后减小, 随交联剂MBA用量增加先增大后减小。同时, PAA-AM-AMPS在沙土中恒温50℃下放置7h后, 保水百分比为75.5%, 说明树脂能提高沙土的饱和含水量, 有效地改良沙土的保水能力, 为沙漠保水提供有效的保水剂。

    Abstract:

    The SAP (Super absorbent polymer) was synthesized by water solution polymerization. The absorbency rate was above 800g/g and the saturation point was within 50mins. The effect of the amount of the co-monomers and cross-linking agent on water-retention capacity at constant pressure and temperature was investigated. The results showed that the water-retention capacity of the SAP were above 30% after being placed at constant pressure for seven days. The results also show that the water-retention capacity increased at first and then decreased with the increase of the amount of acryl-amide and MBA. At the same time, the water-retention rate of the SAP were above 75.5 % after being placed at constant temperature (50℃) for seven hours, which demonstrated that the SPA can improve the saturated water content of the sand and the water-retention capacity of the sand efficiently and will provide the desert with excellent water-retention agent.

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余响林. PAA-AM-AMPS与PAA-AM高吸水性树脂的合成及保水性能[J].精细化工,2011,28(5):

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  • 收稿日期:2011-01-23
  • 最后修改日期:2011-03-08
  • 录用日期:2011-03-09
  • 在线发布日期: 2011-04-13
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