用于可再分散乳胶粉的阳离子苯丙乳液的合成
DOI:
CSTR:
作者:
作者单位:

作者简介:

通讯作者:

中图分类号:

TQ316.334

基金项目:


Synthesis of Cationic Styrene-acrylic latex Used for Redispersible latex Powder
Author:
Affiliation:

Fund Project:

  • 摘要
  • |
  • 图/表
  • |
  • 访问统计
  • |
  • 参考文献
  • |
  • 相似文献
  • |
  • 引证文献
  • |
  • 资源附件
  • |
  • 文章评论
    摘要:

    采用种子乳液聚合法,以十六烷基三甲基溴化铵(CTAB)为乳化剂,偶氮二异丁眯盐酸盐(AIBA)为引发剂,引入亲水性阳离子单体甲基丙烯酰氧乙基三甲基氯化铵(DMC)及功能性单体丙烯酰胺(AM)(DMC与AM的质量比为1:1)来制备用于可再分散乳胶粉的阳离子苯丙乳液。探讨了聚合反应温度、乳化剂用量、引发剂用量、种子单体用量、阳离子单体用量等对乳液及可再分散乳胶粉性能的影响。确定最佳配方和工艺条件为:聚合反应温度在80?℃、CTAB用量为2%、AIBA用量为0.53%、种子单体用量为10.0%,并确定DMC的添加量为2%。在此工艺条件下合成的阳离子苯丙乳液粒径大小和分布适中、性能稳定,由其所制得的可再分散乳胶粉含水率低、平均粒径小、再分散性优良。

    Abstract:

    The cationic styrene-acrylic latex used for redispersible polymer powder was prepared by the method of seeded emulsion polymerization by using cetrimonium bromide(CTAB) as emulsifier, azobisisobutryamide chloride(AIBA) as initiator, and [2-(methacryloyloxy)ethyl]trimethyl-ammonium chloride(DMC) as hydrophilic cationic monomer and acrylamide(AM) as functional monomer while the mass ratio of DMC to AM was 1:1. The effects of polymerization temperature, the amount of emulsifier, initiator, seed monomer, and cationic monomer on polymerization reaction system and properties of latex and redispersible latex powder were investigated. The optional formulation and process condition is that the polymerization temperature is 80±2℃, the amount of CTAB, AIBA, seed monomer and DMC are 2%, 0.53%, 10% and 2% based on total monomers respectively. Then an uniform and stable latex with small particle size and narrow particle size distribution could be obtained. Redispersible latex powder made from this latex has low water content and small average particle size, and also has good redispersibility.

    参考文献
    相似文献
    引证文献
引用本文

高强,沈慧芳.用于可再分散乳胶粉的阳离子苯丙乳液的合成[J].精细化工,2012,29(2):0

复制
分享
文章指标
  • 点击次数:
  • 下载次数:
  • HTML阅读次数:
  • 引用次数:
历史
  • 收稿日期:2011-09-30
  • 最后修改日期:2011-10-28
  • 录用日期:2011-11-07
  • 在线发布日期: 2012-01-09
  • 出版日期:
文章二维码