超细分散染料/乳胶粒复合色素分散体的制备
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Preparation of Ultrafine Disperse Dye/latex Complex Colorants Dispersion
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    摘要:

    采用可聚合乳化剂(DNS-86),通过细乳液聚合制备了超细分散染料/乳胶粒复合色素分散体,考察了助乳化剂、乳化剂、细乳化时间对复合色素分散体性能的影响。结果表明十六烷(HD)助乳化作用较十六醇(CA)、十二硫醇(DDM)好;以DNS-86制备超细分散染料/乳胶粒复合色素分散体的稳定性明显优于传统乳化剂;当DNS-86浓度14.4mmol/L,助乳化剂HD占单体质量的7.5%,细乳化时间15min时,制备超细分散染料/乳胶粒复合色素分散体的粒径为123nm,Npf/Nmi值为1.23,聚合反应以液滴成核为主。

    Abstract:

    Ultrafine disperse dye/latex complex colorants dispersion was prepared through miniemulsion polymerization with polymerizable emulsifier (DNS-86). The influences of co-emulsifier, emulsifier, and ultrasound processing time on properties of complex colorants dispersion were investigated. The results show that hexadecane(HD) was more effective than cetyl alcohol(CA) and dodecanethiol(DDM); The stability of ultrafine disperse dye/latex complex colorants dispersion prepared with DNS-86 was obviously superior to that with conventional emulsifier; When the concentration of DNS-86 was 14.4 mmol?L-1, the weight ratio of cetyl alcohol to monomer was 7.5%, ultrasound processing time was 15min, the ultrafine disperse dye/latex complex colorants dispersion prepared had a diameter of 123nm and Npf/Nmi value of 1.23 ,which indicated that the polymerization was mainly taking place in droplet nucleation.

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罗孝勇,付少海.超细分散染料/乳胶粒复合色素分散体的制备[J].精细化工,2012,29(6):

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  • 收稿日期:2012-01-11
  • 最后修改日期:2012-02-17
  • 录用日期:2012-03-09
  • 在线发布日期: 2012-05-08
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