低熔融粘度C-5石油树脂水基乳液制备研究
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O648.2 3;TQ351.47

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安徽省教育厅重点项目(KJ2011z015);安徽大学211工程项目


Preparation and Research on the Low Melt Viscosity C-5 Petroleum Resin Water-based Emulsion
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    摘要:

    以56#半精炼石蜡为粘度调节剂,研究制备低熔融粘度的C-5石油树脂水基乳液,系统考察了非离子型复合乳化剂的HLB值和用量对石油树脂乳液稳定性、乳液粒径分布、乳液粘度和乳液表面张力的影响。研究结果表明,添加30%的石蜡可以明显降低石油树脂的熔融粘度,使物料在较低温度下实现均匀混合;复合乳化剂的最佳HLB值为10.75;最佳用量为16%。通过正交实验确定了优选乳化工艺条件为:乳化温度98℃、乳化时间20min、剪切速率5000rpm、乳化水占水相的比例为1/3,该条件下可制得固含量为40%,稳定性好、粒径小、粘度低的O/W型C-5石油树脂乳液。

    Abstract:

    A O/W type C-5 petroleum resin emulsion was prepared with paraffin wax as viscosity regulator and blend of nonionic emulsifier. Effect of HLB value and concentration of emulsifier on stability, droplet size, viscosity and surface tension of the petroleum resin emulsion were examined. The results showed that when the paraffin added with 30% percentage composition, the C-5 petroleum resin melt viscosity decreased obviously and the material in the low temperature mixing uniformly. The suitable HLB value is about 10.75 and emulsifier concentration is 16%. The orthogonal experiment results showed that optimum conditions were, emulsifying temperature 98℃, emulsifying time 20 minutes, stirring rate 5000 rpm and emulsifying water quantity 1/3. The O/W type C-5 petroleum resin emulsion which solid content is 40% was prepared under this condition; it showed excellent stability, small droplet size and low viscosity.

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郝家宝,夏茹,苗继斌.低熔融粘度C-5石油树脂水基乳液制备研究[J].精细化工,2012,29(10):

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  • 收稿日期:2012-06-21
  • 最后修改日期:2012-07-28
  • 录用日期:2012-08-29
  • 在线发布日期: 2012-09-14
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