海南核果木果实脂溶性成分的GC-MS分析
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R284.2

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海南大学植物学国家级重点学科(071001)资助;海南省自然科学基金(309001)


GC-MS Analysis of Liposoluble Constituents from Drypetes hainanensis Fruit
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    摘要:

    采用溶剂提取法、硅胶柱层析分离,获得海南核果木果实脂溶性提取物Ⅰ和Ⅱ,结合气相色谱-质谱联用对其化学成分进行分离、鉴定及分析。结果发现,海南核果木果实脂溶性提取物Ⅰ中主要为邻苯二甲酸二(2-乙基己基)酯(64.2%)和烷烃类(23.7%);从脂溶性提取物Ⅱ中鉴定出19种成分,主要为烯烃类(1.4%)、烷烃类(22.9%)、酯类(67.9%)以及植物醇(2.8%)等,酯类主要为饱和脂肪酸酯(35.7%),为软脂酸甲酯(29.0%)和十八碳酸甲酯(6.8%),不饱和脂肪酸酯(18.6%),为11,14-十八碳二烯酸甲酯(10.1%)和6,11-二十碳二烯酸甲酯(8.5%),另外还含有邻苯二甲酸二(2-乙基己基)酯(13.6%)。

    Abstract:

    Identified liposoluble extractⅠand Ⅱfrom Drypetes hainanensis fruit by GC-MS, which were isolated by solvent extraction method and silica column chromatography. The results showed that the main constituents of the extractⅠconsisted of bis(2-ethylhexyl) phthalate (64.2%) and alkanes (23.7%) etc. 19 compounds were found in the extractⅡ, mainly comprised olefin (1.4%), alkanes (22.9%), esters (67.9%) and phytol (2.8%) etc. The esters mainly concluded saturated fatty acid ester (35.7%), which was composed of hexadecanoic acid, methyl ester (29.0%) and octadecanoic acid methyl ester (6.8%), unsaturated fatty acid ester (18.6%), which was constituted by methyl 11,14-octadecadienoate (10.1%) and 6,11-eicosadienoic acid, methyl ester (8.5%), additionally contained bis(2-ethylhexyl) phthalate (13.6%).

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陈德力,孙玉婉,刘平怀.海南核果木果实脂溶性成分的GC-MS分析[J].精细化工,2013,30(2):0

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  • 收稿日期:2012-10-30
  • 最后修改日期:2012-12-20
  • 录用日期:2012-12-20
  • 在线发布日期: 2013-02-25
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