GG-g-PAA/LOESS复合高吸水性树脂的制备与性能
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国家自然科学基金(21164009);教育部长江学者和创新团队发展计划(IRT1177)


Preparation and Properties of GG-g-PAA/LOESS
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    摘要:

    以瓜尔胶(GG)、丙烯酸(AA)和黄土(LOESS)为原料,过硫酸铵(APS)为引发剂,N,N'-亚甲基双丙烯酰胺(MBA)为交联剂,采用水溶液聚合法制备了瓜尔胶接枝聚丙烯酸/黄土(GG-g-PAA/ LOESS)复合高吸水性树脂。采用FTIR和SEM对其结构进行了表征,研究了黄土的添加量对复合高吸水性树脂的溶胀能力和溶胀动力学的影响,考察了复合高吸水性树脂的保水性能、反复溶胀性以及在不同PH溶液中的吸水性能。结果表明:瓜尔胶、丙烯酸和黄土发生了接枝共聚,制备的GG-g-PAA/LOESS复合高吸水性树脂具有良好的吸水倍率、吸水速率、保水性能和反复溶胀性。此外,该复合高吸水性树脂还表现出优异的PH稳定性。

    Abstract:

    guar gum-g-poly(acrylic acid)/loess(GG-g-PAA/LOESS) superabsorbent composites were prepared by graft polymerization in aqueous solution using guar gum (GG), acrylic acid (AA), loess as raw materials, ammonium persulfate (APS) as initiator and N,N-methylenebisacrylamide (MBA) as crosslinker. The structure of superabsorbent composites was characterized by FTIR and SEM. Effects of loess content on swelling capabilities and swelling kinetics of superabsorbent composites was studied. Water-retention properties at various temperatures, reswelling capabilities and water absorbency at various pH solutions of superabsorbent composites were also investigated. The results indicated that GG and LOESS participated in graft polymerization reaction with AA. The prepared GG-g-PAA/LOESS superabsorbent composites have the good properties of water absorbency, water absorption rate, water-retention and reswelling. In addition, the superabsorbent composites showed excellent pH-stability in various pH solutions.

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马国富. GG-g-PAA/LOESS复合高吸水性树脂的制备与性能[J].精细化工,2013,30(12):

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  • 收稿日期:2013-07-01
  • 最后修改日期:2013-08-09
  • 录用日期:2013-08-19
  • 在线发布日期: 2013-11-29
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