AA/AM/AMPS/DAC体膨型堵水剂的合成及其性能研究
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O069

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国家教育部优秀青年教师基金;国家教育部博士点基金


Synthesis and Evaluation of AA/AM/AMPS/DAC Volumetric Swell Type Plugging Agent
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    摘要:

    堵水是目前油田一项控水稳油的重要手段。但由于地层的复杂性,需要堵水剂能够实现耐盐、耐冲刷。本文以丙烯酸(AA)、丙烯酰胺(AM)、2-丙烯酰胺基-2-甲基丙磺酸(AMPS)和丙烯酰氧乙基三甲基氯化铵(DAC)为原料,N,N-亚甲基双丙烯酰胺(MBA)为交联剂,合成了一种体膨型堵水剂。研究了合成条件对产物性能的影响,确定的最优合成条件是:AA与AM质量比4:1,反应温度60℃,引发剂用量0.5%,交联剂用量0.05%,AMPS用量7%,DAC用量4%。合成的堵水剂具有较好的抗盐能力,且在煤油中几乎不膨胀,通过岩心流动实验评价了堵水剂的封堵能力和耐冲刷性能,该堵水剂封堵率能达到86.1%,经过25倍孔隙体积的后续水冲刷,注入压力仅下降少许,该堵水剂具有较强的耐冲刷能力。

    Abstract:

    Water plugging is an important means for the field to stabilize oil production and to control water cut. Due to the complexity of the formation, the plugging agent needs salt tolerance and washing stability. A swellable type blocking agent was synthesized by copolymerizing using acrylic acid (AA), acrylamide (AM), 2 - acrylamido - 2 - methylpropane sulfonic acid (AMPS), and acryloyloxyethyl trimethyl ammonium chloride (DAC) as monomer, N, N-methylene-bis-acrylamide (MBA) as a cross-linking agent. The effects of reaction conditions on the properties were studied and the optimal synthesis conditions were determined as follow: mass ratio of AA to AM was 4:1, the reaction temperature was 60 ℃, the amount of initiator, cross-linking agent, AMPS, DAC and MBA were 0.5% , 0.05%, 7% and 4% separately. The blocking agent had good salt tolerance and hardly expanded in kerosene. Plugging ability and resistance to scour of the plugging agent were evaluated by core flow tests and the plugging agent plugging rate reached 86.1% and injection pressure decreased slightly, after more than 25 times pore volume subsequent water scouring. The blocking agent had a strong resistance to erosion capacity.

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赖南君. AA/AM/AMPS/DAC体膨型堵水剂的合成及其性能研究[J].精细化工,2014,31(8):

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  • 收稿日期:2014-03-13
  • 最后修改日期:2014-05-14
  • 录用日期:2014-05-27
  • 在线发布日期: 2014-08-05
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