耐高温、耐强碱性有机硅消泡剂的配制及应用研究
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Preparation of Organic Silicone Defoamer that Resisting to High Temperature and Strong Alkali and its Application
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    摘要:

    在铂催化下,将含氢硅油(PHMS)和烯丙基聚醚(APE)进行硅氢化加成反应,合成了聚醚改性硅油(PESO),并用傅里叶红外光谱(FT-IR)对其进行了结构表征。以聚醚改性硅油、自制硅膏、液体石蜡为原料,并配加复合型乳化剂S和其他助剂,以机械乳化法制得聚醚有机硅消泡剂(XP)。研究结果表明,在乳化水温为70℃、乳化时间为40min的条件下所制备的消泡剂XP具有水分散性好、快速消泡和持久抑泡的效果,XP的消泡时间为5s,抑泡时间达60min。且所制的消泡剂在100℃高温和pH=14的强碱条件下消泡时间约为6s,抑泡时间约为50min。

    Abstract:

    polyether modified silicone oil (PESO) was hydrosilylated from hydrogen content silicone(PHMS)and allyl polyether(APE)in the presence of Pt catalyst, the structure of the product was investigated by IR. Polyether modified silicone oil, self-made silicone paste and liquid paraffin as the raw material, together with the compound emulsifier S and other additives, polyether organosilicone defoamer was successively prepared with mechanical emulsification. The results showed that the defoamer was compounded in the conditions of emulsification temperature 70℃ and emulsification time 40min was characterized by better water-solubility, speedy defoaming ability and long-term inhabitation of foam, XP defoaming time is 5s, and the time of foam inhibiting performing is 60min. And the XP defoaming time is about 6s, the time of foam inhibiting performing is about 50min in constant of high temperature of 100℃ and strong alkali of pH 14.

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王婷婷.耐高温、耐强碱性有机硅消泡剂的配制及应用研究[J].精细化工,2014,31(10):

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  • 收稿日期:2014-05-06
  • 最后修改日期:2014-06-10
  • 录用日期:2014-06-23
  • 在线发布日期: 2014-09-22
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