微波辐射制备阿拉伯胶接枝2-丙烯酰胺基-2-甲基丙磺酸高吸水树脂及溶胀性能
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Preparation and Swelling Properties of Gum Arabic Graft AMPS Superabsorbent Resin by Microwave Irradiation
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    摘要:

    以阿拉伯胶(GA),2-丙烯酰胺基-2-甲基丙磺酸(AMPS)为原料,N,N-亚甲基双丙烯酰胺(NMBA)为交联剂,过硫酸钾(APS)为引发剂,采用微波辐射方法制备了GA-g-PAMPS 高吸水性树脂。探讨了单体配比、交联剂用量、引发剂用量、中和度、微波功率和辐射时间对吸水倍率的影响,研究了树脂的溶胀性能,并用FTIR对吸水性树脂的结构进行了表征。结果表明:最佳合成条件下树脂吸去离子水倍率为683g/g,吸生理盐水倍率为137g/g。树脂的吸水倍率随着无机盐溶液浓度的增加而减小,在不同价态金属离子盐溶液中,树脂的吸水倍率顺序为NaCl>BaCl2> FeCl3,树脂具有较高的吸水速率和较好的重复吸水性能。

    Abstract:

    A novel gum arabic-g-poly(2-acrylamido-2-methylpropanesulfonicacid) superabsorbent resin was synthesized by aqueous solution polymerization using microwave irradiation in the presence of potassium persulfate (KPS) as a initiator and N, N-methylene-bis-acrylamide (NMBA) as a crosslinking agent. The effects of the mass ratio of AMPS to GA, crosslinker, initiator, neutralization degree, power and time on the water absorbency of superabsorbent resin were investigated systematically, and the swelling properties of superabsorbent resin were studied. The chemical micstructure of GA-g-PAMPS superabsorbent resin was determined by FTIR. Under the optimum reaction conditions,the water absorbency of superabsorbent resin is 683g/g in the deionized water and 137g/g in normal saline. The water absorbency of the superabsorbent resin decreases with increasing concentration of various external saline solutions, and has the following tendency in different metal ions saline solutions: NaCl>CaCl2> FeCl3,The superabsorbent resin has a high water absorbent rate and a good reswelling capability。

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甘颖.微波辐射制备阿拉伯胶接枝2-丙烯酰胺基-2-甲基丙磺酸高吸水树脂及溶胀性能[J].精细化工,2015,32(1):0

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  • 收稿日期:2014-06-17
  • 最后修改日期:2014-07-24
  • 录用日期:2014-08-14
  • 在线发布日期: 2014-12-18
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