硼钛复合交联剂的制备及其在葫芦巴胶压裂体系中的应用
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咸阳市科技计划项目(2013K05-06)


Preparation and Application of Boron-titanium Composite Crosslinking Agent in Fenugreek Gum Fracturing System
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    摘要:

    以四硼酸钠、钛酸丁酯、三乙醇胺、甘油、乙二醇为原料,合成了有机硼钛交联剂,制备了葫芦巴胶压裂液。研究了主剂及配体物料比,反应温度与反应时间对交联剂成胶性能的影响。结果表明,m(四硼酸钠):m(钛酸丁酯)=1:4,m(三乙醇胺):m(甘油)=1:2,反应温度70℃,反应时间3h的条件下,合成的交联剂性能最优。考察了w(葫芦巴胶溶液)=0.4%,m(葫芦巴胶溶液):m(硼钛交联剂)=100:(0.4~0.6)时,葫芦巴胶压裂液的性能,交联延时150s,耐温耐剪切性能良好;常温下,携砂比V(压裂液):V(石英砂)=70:30时,沉降速度0.009mm•s-1;体系易破胶,破胶液黏度低于5mPa•s,对储层伤害小。

    Abstract:

    For fenugreek gum thickener,now using sodium tetraborate,butyl titanate, triethanolamine,glycerin and glycol as raw materials,organic titanium boron crosslinking agent was synthesized,and fenugreek gum fracturing fluid was prepared. The study has studied the effects of the main agent and ligand material ratio,reaction temperature and reaction time on the properties of crosslinking agent gelling.The results showed that the m(sodium tetraborate):m(butyl titanate)=1:4,m (triethanolamine):m(glycerin)=1:2,reaction temperature 70℃,reaction time is 3h, crosslinking agent has the optimal performance.Examined the w(fenugreek gum solution)=0.4%,crosslinking ratio m(fenugreek gum solution):m(titanium boron crosslinking agent)=100:(0.4~0.6),the fenugreek gum fracturing fluid performance shows that:the delayed time was 150s,the shearing resistance and temperature tolerance were good;Under normal temperature,when the sand ratio was 30% in volume,the settling velocity was 0.009mm•s-1;Gel breaking liquid viscosity is lower than 5mPa•s,and it is less damage to the reservoir.

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环灿灿.硼钛复合交联剂的制备及其在葫芦巴胶压裂体系中的应用[J].精细化工,2015,32(1):0

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  • 收稿日期:2014-07-03
  • 最后修改日期:2014-08-25
  • 录用日期:2014-09-15
  • 在线发布日期: 2014-12-18
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