温致变色涂料制备及变色性能研究
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TS 190.2

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国家自然科学基金(21174055)


Synthesis and Chromatism Properties of Thermochromic Coating
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    摘要:

    以三芳甲烷类隐色体染料为发色剂,配合显色剂和溶剂合成了适用于织物应用的温致变色涂料。考察了溶剂复配,发色剂、显色剂、溶剂种类对温变涂料颜色及颜色变化的影响。探讨了涂料添加对温变涂料颜色调节作用。结果表明,在温变涂料中添加涂料能有效改变温致变色涂料颜色并且不影响其温致变色能力和变色温度;发色剂、显色剂、溶剂间极性不同会破坏温变涂料温变色能力;制备温变涂料所用溶剂为十六醇与十二醇质量比4:1和3:2时, 温变涂料变色温度分别为42 °C和 36 °C,说明改变溶剂比例能有效调控温变涂料变色温度。

    Abstract:

    Thermochromism coating was synthesized using triarylmethane leuco dye-based as color former, color developer and alcohols to realize the application for fabric. The effects of mixing solvents, kinds of color former, color developer and solvents on the color and chromatism of the thermochromism coating were analyzed. The color tenability was discussed by adding coatings into thermochromism coating. The results were showed that by adding coatings into thermochromism coating can effectively change the color of thermochromism coating without changing the chromatism temperature; the thermochromism ability can be damaged if the polar between the color former, color developer and solvents was different; color-transition temperature of thermochromism coating that was synthesized using hexadecyl alcohol: lauryl alcohol (mass ratio) = 4:1 was 42 °C. When using hexadecyl alcohol: lauryl alcohol (mass ratio) =3:2, the color-transition temperature of thermochromism coating was 36 °C, indicated changing the solvents ratios can effectively control the color-transition temperature of thermochromism coating.

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张婉,黄荣桓,孟秋迪,王潮霞,殷允杰.温致变色涂料制备及变色性能研究[J].精细化工,2015,32(9):

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  • 收稿日期:2015-04-21
  • 最后修改日期:2015-05-29
  • 录用日期:2015-06-02
  • 在线发布日期: 2015-08-12
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