氯化1-(三甲基硅甲基)-3-癸基咪唑的合成及性能
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Synthesis and Properties of 1-(threetrimethylsilylmethyl)-3-decyl imidazolium Chloride
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    摘要:

    以咪唑、氢氧化钠和溴代癸烷为原料,经烷基化反应合成了中间体N-癸基咪唑,再与氯甲基三甲基硅烷在未经改装的家用微波炉中进行季铵化反应合成了离子液体型表面活性剂氯化1-(三甲基硅甲基)-3-癸基咪唑。通过IR、1HNMR和13CNMR对中间体和目标产物的结构进行了表征,同时测定了目标产物的热稳定性、泡沫性能及表面活性。结果表明,氯化1-(三甲基硅甲基)-3-癸基咪唑在297℃时基本分解完全,并且起泡力随表面活性剂浓度的升高而增强,但不同浓度下的稳泡性均较差。此外,该离子液体型表面活性剂在25℃时的临界胶束浓度(cmc)为4.12mmol/L,临界胶束浓度时的表面张力(γcmc)为25.13mN/m,具有优良的表面活性。

    Abstract:

    A kind of ionic liquid surfactant 1-(threetrimethylsilylmethyl)-3-decyl imidazolium chloride was prepared in an unmodified microwave oven by quaternary ammonium reaction of chloromethyltrimethylsilane with N-decyl imidazole, which was synthesized using imidazole, sodium hydroxide and bromodecane as materials through alkylation reaction. The structure of the intermediate and the target product were characterized by IR、1HNMR and 13CNMR. At the same time, the thermal stability, foaming properties and surface activities of the target product were measured. The results show that complete decomposition temperature of 1-(threetrimethylsilylmethyl)-3-decyl imidazolium chloride was 297℃. The foaming power increased with increasing concentration of the surfactant, but the foam stability at different concentration was low. Moreover, the critical micelle concentration (cmc) of the ionic liquid surfactant was 4.12mmol/L and the surface tension at cmc was 25.13mN/m at 25 ℃.

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李静静,赵地顺,胡晶晶,刘静,任培兵.氯化1-(三甲基硅甲基)-3-癸基咪唑的合成及性能[J].精细化工,2015,32(12):0

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  • 收稿日期:2015-07-22
  • 最后修改日期:2015-09-12
  • 录用日期:2015-09-28
  • 在线发布日期: 2015-12-10
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