一种新型环氧树脂潜伏性固化剂二苯基双胍的合成与性能
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TQ436

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国家自然科学基金资助项目(No.51173204, 2014A030310412) ; 广东省产学研项目(No.2012B090400036);广东省自然科学基金(No.2015A030313822, 2015A030313799)。


Synthesis and Properties of a Novel Bis-phenylbiguanide as Latent-curing Agent for Epoxy Resin
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    摘要:

    双氰胺是环氧树脂的一种常用固化剂,为了提高双氰胺固化剂的综合性能,我们设计合成了一种新型的环氧树脂潜伏性固化剂二苯基双胍。采用FTIR和1H NMR表征了固化剂的化学结构,并通过DSC分析得到环氧树脂与固化剂的最佳质量配比为5:1,固化活性实验及凝胶实验分析得到最佳固化温度为130 ℃和储存期为室温下30 d,拉伸实验分析了固化物的抗拉强度可达38.07 Mpa,以及采用TG测试得到固化物的热分解温度超过270 ℃。结果表明,与双氰胺环氧树脂固化体系相比,新型固化剂和环氧树脂有更好的相容性,潜伏性良好,其固化温度降低30 ℃以上,固化物有更优异的力学性能和良好热稳定性。

    Abstract:

    Dicyandiamide is commonly used as curing agent in epoxy resin. A new latent curing agent for epoxy resin was synthesized to improve the comprehensive performance of dicyandiamide curing agent. The chemical structure of curing agent was characterized by FTIR,1H NMR. The optimum ratio of epoxy resin and curing agent was 5:1 under the assistance of DSC. The optimum curing temperature and storage time in room temperature was 130 ℃ and 30 d obtained by curing activity test and gel test, respectively. Tensile strength of cured epoxy resin was 38.07 MPa, which is analyzed by tesion test. Thermal decomposition temperature of the cured epoxy was exceeded 270 ℃ with the help of TG. Comparing with dicy/epoxy resin curing system, the new agent has better compatibility with epoxy resin. Its latency performance was fine and curing temperature was decreased more than 30 ℃ and the cured epoxy has excellent mechanical properties and good thermostabilities.

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王永超,林树东,涂园园,李江华,胡继文,李妃.一种新型环氧树脂潜伏性固化剂二苯基双胍的合成与性能[J].精细化工,2016,33(2):

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  • 收稿日期:2015-11-30
  • 最后修改日期:2015-12-22
  • 录用日期:2015-12-30
  • 在线发布日期: 2016-01-13
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