埃洛石纳米管/水性环氧树脂复合材料的性能
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TQ338

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西安市未央区科技计划项目(201505);陕西省教育厅重点实验室项目(2011JS057);陕西省科技计划项目(2015KJXX-35)


Properties of Halloysite Nanotubes/Waterborne Epoxy Resin Composites
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    摘要:

    采用超声分散与机械搅拌混合方法制备了埃洛石纳米管/水性环氧树脂复合材料。通过透射电镜(TEM)、扫描电镜(SEM)等对埃洛石(HNTs)及复合材料的结构形貌进行了表征。结果表明,埃洛石为规整的中空纳米管结构,可在水性环氧树脂体系中分散均匀,复合材料由脆性断裂转变为韧性断裂;但当埃洛石含量高于5%,复合材料出现明显团聚。详细分析了HNTs的添加量对水性环氧树脂的流变行为、热稳定性及涂膜性能的影响。适量HNTs的加入,可提高体系的热稳定性,可使复合体系粘度和储能模量增加,内耗降低,起到类交联点的作用,增强复合体系的稳定性,最佳含量为2%。复合体系呈现假塑性和明显的触变性。同时,HNTs的加入可有效改善环氧树脂的耐水性能,增强涂膜的硬度及柔韧性。但HNTs含量过高,会破坏体系结构与稳定性,使得涂膜综合性能下降。

    Abstract:

    Halloysite nanotubes(HNTs)/waterborne epoxy resin composite material was prepared through ultrasonic dispersion and mechanical blending. The morphology of HNTs and composites were characterized by transmission electron microscopy(TEM) and scanning electron microscopy(SEM). It was found that HNTs displayed as nanotubes with hollow structure. HNTs were able to disperse uniformly in composites when HNTs content was lower than 2%. The fracture characteristic of film transferred from brittle fracture to ductile fracture. However, aggregation took place when the HNTs content was greater than 5%. Effects of HNTs content on the rheology, thermal stability and film performance of waterborne epoxy system were systematically investigated. The results showed that the thermal stability of composites was enhanced with the HNTs addition, The viscosity and storage modulus were increased with appropriate amount of HNTs, and the loss factor decreased. It suggested that the HNTs can functionalized as crosslinking points in composites and thereby improve the composite stability, and the optimum content was 2%. In addition, the water resistance of composite was enhanced, as well as the hardness and flexibility of film. However, excessive HNTs would destroy the crosslinking structure and be unfavorable to the stability and comprehensive properties of composite films.

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于凯烁,杨军,王海花.埃洛石纳米管/水性环氧树脂复合材料的性能[J].精细化工,2016,33(10):

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  • 收稿日期:2016-03-02
  • 最后修改日期:2016-06-07
  • 录用日期:2016-06-30
  • 在线发布日期: 2016-09-13
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