GA-g-PAMPS/APT复合高吸水性树脂的合成和溶胀行为
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安徽高校自然科学研究项目(KJ2016A197);大学生创新创业训练计划项目(AH201510361249)


Synthesis and Swelling Behaviors of GA-g-PAMPS /APT Superabsorbent Resin
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    摘要:

    以阿拉伯胶(GA)、2-丙烯酰胺基-2-甲基丙磺酸(AMPS)、凹凸棒石黏土(APT)为原料,采用微波辐射法,通过接枝共聚合成了生物质GA-g-PAMPS /APT高吸水性树脂,利用FTIR、XRD和TG分析了树脂的结构和热稳定性能,探讨了树脂在各种盐溶液和不同pH溶液的溶胀行为,研究了树脂的溶胀速率和反复吸水性能。结果显示:GA,APT与AMPS之间发生了接枝共聚反应, w(GA)=7.5%,w(APT)=10%时树脂在去离子水和生理盐水中的最大吸水倍率分别为783g/g和91g/g。树脂在各种盐溶液和pH溶液中表现出良好的响应性和可逆性能。适量引入APT能显著提高树脂的热稳定性、溶胀速率、反复吸水性能和pH稳定性。

    Abstract:

    Novel gum arabic (GA)graft 2-acrylamido-2-methylpropanesulfonicacid (AMPS) and attapulgite (APT) biomass resin (GA-g-PAMPS /APT) was synthesized by grafting polymerization using microwave irradiation. The structure and thermal stability of superabsorbent resin were characterized by FTIR, XRD and TG , respectively. The effects of various saline and pH solutions on swelling properties were investigated,and the swelling rate and reswelling capacity were also evaluated. The results showed that GA, APT and AMPS produced the grafting copolymerization reaction. The resin containing w(GA)=7.5% and w(APT)=10% showed the highest water absorbency of 783 g/g and 91 g/g in the deionized water and in normal saline, respectively. The resin showed excellent responsive properties and reversible characteristics in pH and salt solutions. The introduction of APT into simultaneously the polymeric network obviously improved the thermal stability, the swelling rate, reswelling capability and pH resistant property.

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徐继红. GA-g-PAMPS/APT复合高吸水性树脂的合成和溶胀行为[J].精细化工,2016,33(7):

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  • 收稿日期:2016-03-22
  • 最后修改日期:2016-05-02
  • 录用日期:2016-05-13
  • 在线发布日期: 2016-06-06
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