一种聚丙烯酰胺压裂液减阻剂的合成及性能分析
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Synthesis and Properties of Polyacrylamide Drag Reducer for Fracturing Fluid
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    摘要:

    为了降低压裂施工摩阻,增大泵注排量,以丙烯酰胺、3-烯丙基-2-羟基-1-丙烷磺酸钠和丙烯酸十八酯为原料,采用反相乳液聚合方式合成出聚丙烯酰胺压裂液减阻剂,用傅里叶红外光谱和扫描电镜对产物结构和形貌进行表征,考察了压裂液减阻剂的减阻性、溶解性、耐剪切性、粘弹性和配伍性等性能,实验结果表明:聚丙烯酰胺乳液被成功合成,该乳液的固含量为29.6%,粘均分子量为8.5×105g/mol,乳液粘度为1800mPa.s;在剪切速率为6.8m/s时,乳液溶解时间为48s;在剪切速率为10m/s,剪切时间为300s时,减阻率保持在70%,耐剪切性能较好;在室温下、剪切速率为10m/s、质量分数为1g/L时,压裂液减阻剂的减阻率为78%,减阻率随着减阻剂质量分数的增大先逐渐增大后保持平衡;粘弹性测试表明聚合物属于粘弹性结构流体,在剪切频率为1Hz,应力变化为5%时,体系的储能模量大于耗能模量且保持稳定;配伍性测试中表明在剪切速率10m/s、质量分数为1g/L、温度为80℃和矿化度为20000mg/L时,聚合物减阻率为53%,助排剂和黏土稳定剂对减阻剂无影响。

    Abstract:

    For reducing fracturing pressure and increasing pump output volume,A of water-soluble drag reducing agent emulsion was synthesized by using acrylamide,octadecyl acrylate and 2-hydroxy-3-(2-propenyloxy)-1-propanesulfonicacimonosodiumsalt as raw materials by inverse emulsion polymerization. The chemical structure and surface morphology of polymer were characterized by means of FTIR and SEM. In addition, the ability of solubility, drag reducing rate, shear resistance, viscoelasticity and cooperation were investigated. Results showed that the solid content of emulsion was 29.6%, the viscosity average molecular weight was 8.5×105g/mol, the viscosity of emlusion was 1800mPa.s. the dissolusion time of polymer was 48s at shear rate of 6.8m/s. the drag reducing rate of polymer exceeds 70% at 10m/s and 300s. the concentration of 1g/L drag reduction agent in aqueous exceed 78% at shear rate of 10m/s. The drag reduction test showed that the drag reduction rate of polymer increased at first and stable latter with the increment of the polymer. Viscoelasticity result shown that the polymer was viscoelastic structure fluid, the value of storage modulus (G') is larger than loss modulus (G'') at 1Hz and 5%. The drag reduction rate of polymer exceeds 53% at 10m/s, 1g/L, 80℃ and 2000mg/L, the additive and clay stabilizer have no effect to drag reducing rate of polymer.

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张锋三.一种聚丙烯酰胺压裂液减阻剂的合成及性能分析[J].精细化工,2016,33(12):

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  • 收稿日期:2016-04-28
  • 最后修改日期:2016-08-23
  • 录用日期:2016-09-19
  • 在线发布日期: 2016-11-16
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