含吡啶结构丙烯酰胺共聚物驱油剂合成及性能
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油气田应用化学四川省重点实验室开放基金(YQ究团KF201404);四川省青年科技创新研队(2015TD0007);四川省科技支撑计划(2016GZ0274);西南石油大学课外开放实验(KSP15121)


Synthesis and Properties of Acrylamide-Based Copolymer Containing Pyridine Unit as EOR Chemical
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    摘要:

    以丙烯酰胺(AM)、丙烯酸(AA)、N-烯丙基油酰胺(NAE)和3-烯丙胺基羰基-1-乙基吡啶溴化铵([m-AEPy]Br)为单体,采用氧化还原引发体系,制备了一种含吡啶离子液体结构疏水缔合聚合物驱油剂AM/AA/NAE/[m-AEPy]Br。对共聚物进行了红外、核磁表征,并研究了其增粘性、剪切稀释性、耐温抗盐性等性能,对其提高采收率能力进行了评价。结果表明:2000 mg/L的共聚物溶液表观粘度可达510.3 mPa穝;在剪切速率为510 s-1下,其粘度保留值为27.2 mPa穝,且在90 oC时表观粘度可保留42.8 mPa穝;在10000 mg/L NaCl、1500 mg/L MgCl2和CaCl2溶液中,其表观粘度分别为21.8,27.4和27.0 mPa穝;在模拟驱油实验中,共聚物溶液的采收率提高了11.4%

    Abstract:

    A hydrophobic association polymer containing pyridine ionic liquid was synthesized by oxidation-reduction initiator system using acrylamide, acrylic acid, N-allyl oleamide and 3-allylaminocarbonyl-1-ethylpyridine bromide. The copolymer was characterized by IR and 1H NMR, and the thickening property, shear thinning, temperature resistance, salt tolerance and flooding capability of it were studied. The results showed that the apparent viscosity of 2000 mg/L copolymer solution could reach 510.3 mPa穝, and it could remain 27.2 mPa穝 under 510 s-1 and 42.8 mPa穝 at 90 oC. When the copolymer was dissolved in 10000 mg/L NaCl、1500 mg/L MgCl2 and CaCl2 solutions, the apparent viscosity of them were 21.8,27.4 and 27.0 mPa穝, respectively. The stimulating displacement experiment indicated that the recovery ratio of copolymer solution was enhanced 11.4%.

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张勤,苟绍华.含吡啶结构丙烯酰胺共聚物驱油剂合成及性能[J].精细化工,2017,34(1):

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  • 收稿日期:2016-07-13
  • 最后修改日期:2016-08-23
  • 录用日期:2016-09-21
  • 在线发布日期: 2016-12-23
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