海藻酸钠衍生物对水乳液在靶标表面行为的影响
DOI:
CSTR:
作者:
作者单位:

作者简介:

通讯作者:

中图分类号:

TQ423

基金项目:

国家自然科学基金(21366010,21566009);海南省自然科学基金(213010,20162013,20162016);海南省重点科技计划(cxy20150026);海南省水环境污染治理与资源化重点实验室开放基金资助


Effect of Alginate Derivative on the behavior of Water Emulsion on Target Surface
Author:
Affiliation:

Fund Project:

  • 摘要
  • |
  • 图/表
  • |
  • 访问统计
  • |
  • 参考文献
  • |
  • 相似文献
  • |
  • 引证文献
  • |
  • 资源附件
  • |
  • 文章评论
    摘要:

    摘要:采用反相乳化法制备了以烷基糖苷(APG)为乳化剂的高效氯氟氰菊酯水乳液。并测定了药液的动、静态表面张力、接触角以及在香蕉叶片上的持留量和药物吸附量,考察了胆固醇改性海藻酸钠衍生物(CSAD)对载药水乳液在叶片上的润湿性和沉积量的影响。结果表明:CSAD+APG体系和APG单独体系稳定的水乳液中表面活性剂(APG)的临界胶束浓度均为CAPG= 0.1 g/L。当CAPG = 0.1 g/L时,两种体系药液的最大持留量分别为0.0104和0.007 78 g/cm2,粘附张力分别是24.32和16.14 mN/m,粘附功分别是55.23和46.47 mN/m;在叶片上的药物吸附量分别为524和412 μg/L。由此推断:两亲性嵌段聚合物CSAD是通过疏水作用与APG形成混合胶束吸附在固液界面,有效地提高了药液在叶片上的持留量和药物吸附量。

    Abstract:

    Abstract:Effect of cholesteryl grafted sodium alginate derivative (CSAD) on wettability and deposition capacity of lambda-cyhalothrin in water emulsion on the banana leaf surface was investigated in terms of dynamic and static surface tension, contact angle, retention and pesticide adsorption capacity by the inverse emulsion method, which was adopted to prepare the lambda-cyhalothrin in water emulsion by alkyl indican (APG) as the emulsifie. The results showed that both the CSAD+APG system and the APG system stable water emulsion had a similar critical micelle concentration(i.e., 0.1 g/L of CAPG). In addition, for the two systems as the CAPG was equal to 0.1 g/L, the maximum retention capacity on leaves was 0.0104 and 0.00778 g/cm2, the adhesion tension was 24.32 and 16.14 mN/m and the adhesion work was 55.23 and 46.47 mN/m, respectively. Furthermore, the CSAD+APG system showed a much higher pesticide adsorption capacity on leaves that was 524 μg/L, while the corresponding value of the APG system was only 412 μg/L. In general, the addition of the amphiphilic CSAD could effectively enhance the retention and adsorption capacity of water emulsion on banana leaves due to the formation of CSAD-APG complexes adsorbed at the solid-liquid interface.

    参考文献
    相似文献
    引证文献
引用本文

肖敦抄,冯玉红.海藻酸钠衍生物对水乳液在靶标表面行为的影响[J].精细化工,2017,34(2):

复制
分享
文章指标
  • 点击次数:
  • 下载次数:
  • HTML阅读次数:
  • 引用次数:
历史
  • 收稿日期:2016-08-05
  • 最后修改日期:2016-10-21
  • 录用日期:2016-11-09
  • 在线发布日期: 2017-01-18
  • 出版日期:
文章二维码