量子点敏化太阳电池FTO/CoS/CuS对电极的制备与性能
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TM914.4

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国家自然科学基金(21576195和21506151)


Preparation and Characterization of FTO/CoS/CuS Composite Counter Electrode for Quantum Dot Sensitized Solar Cells
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    摘要:

    摘要:本文采用恒电位电沉积方法在FTO导电玻璃表面依次沉积CoS和CuS,形成 FTO/CoS/CuS复合对电极用于量子点敏化太阳电池。确定了电沉积电位和电沉积时间,并研究了电沉积温度对电极形貌及电催化活性的影响。对电极的表面形貌和微观结构采用SEM和TEM方法进行表征;对电极的光反射性能采用紫外可见分光光度计进行测试;对电极的电化学性能通过测试交流阻抗、Tafel极化曲线以及J-V曲线进行表征。研究结果表明,FTO/CoS/CuS对电极与电解液界面处的电荷转移阻抗较低,具有更高的光反射率及电催化活性。与Au片、FTO/CoS和FTO/CuS对电极相比,光电转化效率分别提高了132.9%,46.6%,26.9%。

    Abstract:

    Abstract:In this paper, CoS and CuS were potentiostatic deposited sequentially on the surface of FTO conductive glass substrate to fabricate the FTO/CoS/CuS composite counter electrode for quantum dot sensitized solar cells. FTO/CoS/CuS composite counter electrode was prepared at a suitable voltage and electrodeposition time, and the effects of electrolytic temperature on the morphology and electrocatalytic activity of prepared counter electrode were studied. The morphology and microstructure of counter electrode were determined by SEM and TEM. UV-VIS was used to investigate the optical reflection property of counter electrode. The electrochemical impedance spectroscopy, Tafel-polarization measurments and J-V curves were used to characterize the electrochemical performance. The result indicates that FTO/CoS/CuS composite counter electrode provides higher reflectivity, superior electrocatalytic activity and lower charge-transfer resisitance at the interface of counter electrode/electrolyte. Compared with that of Au, FTO/CoS and FTO/CuS counter electrode, the photovoltaic conversion efficiency of FTO/CoS/CuS composite counter electrode is increased by 132.9%, 46.6% and 26.9%, respectively.

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黄晓宇,马换梅,汪天洋,周雪琴,田建华.量子点敏化太阳电池FTO/CoS/CuS对电极的制备与性能[J].精细化工,2017,34(9):

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  • 收稿日期:2016-11-09
  • 最后修改日期:2017-03-29
  • 录用日期:2017-04-17
  • 在线发布日期: 2017-08-03
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