氮掺杂多孔石墨碳的制备及储能特性
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国家自然科学基金青年资助项目(21501104,21601018);黑龙江省自然科学基金项目(B2015014);黑龙江省普通本科高等学校青年人才培养计划(UNPYSCT-2016088)


Synthesis and Energy Storage Properties of Nitrogen-doped Porous Graphite Carbon
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National Natural Science Foundation of China (21501104,21601018), the Natural Science Foundation of Heilongjiang Province (B2015014). The University Nursing Program for Young Scholars with Creative Talents in Heilongjiang Province (UNPYSCT-2016088)

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    摘要:

    摘要:为得到高储能特性的超级电容器电极材料,以价格低廉的生物质——海带为碳源、三聚氰胺为氮源,通过聚合-NaOH活化法合成出纳米级氮掺杂多孔石墨化碳材料(NPGC)。通过XRD、BET、Raman和XPS测试手段表征,结果显示:片层结构的NPGC具有大的比表面积(1771 m2/g)、高的氮含量(6.27at%)和良好的石墨化强度(ID/IG:2.84)并对材料进行了循环伏安、恒电流充放电和交流阻抗性能测试,结果表明:在电流密度为1 A/g时,其电容高达267 F/g, 5 000次恒流充放电循环后,其比电容仍为初始电容的99.9%。因此, 该法制备的氮掺杂纳米级多孔石墨化碳具有优异的储能特性。

    Abstract:

    Abstract:To obtain electrode materials with high performance of supercapacitor, porous graphite carbon with high nitrogen level (NPGC) was prepared via a novel aggregation-NaOH activation route, in which low-cost kelp and melamine severed as carbon and nitrogen source, respectively. The as-prepared samples were characterized by XRD, BET, Raman and XPS. The results showed that the resulting NPGC with a lamellar structure displayed a large surface area of 1771 m2/g and a high graphite degree (ID/IG:2.84) and possessed a high nitrogen content of 6.27at%. In addition, the electrochemical properties of the samples were examined using cyclic voltammetry (CV), galvanostatic charge-discharge (GCD) and electrochemical impedance spectroscopy (EIS). As a result, the specific capacitance of the NPGC material reached up to 267 F/g at 1 A/g. Furthermore, the specific capacitance of the sample was still 99.9% of the initial specific capacitance after 5000 cycles. Thus, the synthesized material had excellent energy storage properties.

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孙立,徐立洋,李宏扬,杨颖.氮掺杂多孔石墨碳的制备及储能特性[J].精细化工,2018,35(10):

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  • 收稿日期:2017-09-17
  • 最后修改日期:2018-03-12
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  • 在线发布日期: 2018-10-08
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