GO/GA-g-PAMPS复合水凝胶的制备及阳离子染料吸附性能
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TQ424.3

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安徽高校自然科学研究项目(KJ2016A197)


Preparation of GO/ GA-g-PAMPS Composite Hydrogels and Study on Dye Adsorption Properties
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Supported by Natural Science Foundation of Anhui universitiy(KJ2016A197)

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    摘要:

    以自制氧化石墨烯(GO)和阿拉伯胶(GA)、2-丙烯酰胺基-2-甲基丙磺酸(AMPS)为原料,采用一步水热反应法制备了GO/GA-g-PAMPS新型复合水凝胶,利用FTIR、XRD、SEM对复合水凝胶结构进行了表征。研究了GO浓度、溶液pH、染料初始浓度、吸附时间、吸附温度对阳离子染料亚甲基蓝(MB)和结晶紫(CV)吸附性能的影响。结果显示:水凝胶对阳离子染料具有较好的吸附效果,在GO浓度为0.3mol/mL,凝胶用量为0.05g,溶液pH为7,温度为50℃,染料初始浓度为200mg/L时,凝胶对MB和CV的吸附量和吸附率分别为395.68、381.70mg/g和98%、96%。凝胶经过5次循环使用后,对MB和CV的吸附率仍能达到82.6%和81.2%。吸附等温线和动力学研究表明,凝胶对MB吸附更符合Freundlich模型,对CV的吸附更符合Langmuir模型,准二级动力学模型能更好地描述两种阳离子染料的吸附过程。热力学研究表明水凝胶对两种染料吸附是自发、吸热和混乱度增加的过程。

    Abstract:

    GO/GA-g-PAMPS composite hydrogel was prepared by one-step hydrothermal reaction with Graphene Oxide (GO), gum Arabic (GA) and 2-acrylamide-2-methylpropanesulfonic acid (AMPS) as raw materials.The structure of the hydrogel was characterized by FTIR, XRD and SEM.The effects of GO concentration, solution pH, initial dye concentration, adsorption time and adsorption temperature on the adsorption properties of cationic dyes methylene blue (MB) and crystal violet (CV) were studied.The results showed that the hydrogel had a good adsorption effect on cationic dyes. When the GO concentration was 0.3mol/mL, the gel dosage was 0.05g, the solution pH was 7, the temperature was 50℃, and the initial dye concentration was 200mg/L, the adsorption capacity and adsorption rate of the gel on MB and CV were 395.68, 381.70mg/g and 98% and 96%, respectively.After 5 cycles, the adsorption rates of MB and CV were still up to 82.6% and 81.2%.The adsorption isotherm and kinetics showed that the adsorption of MB by gel was more consistent with Freundlich model, while the adsorption of CV was more consistent with Langmuir model, and the quasi-second-order kinetic model could better describe the adsorption process of two cationic dyes.Thermodynamic studies showed that the adsorption of the two dyes by the composite hydrogel is spontaneous, endothermic and chaotic.

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何梦奇. GO/GA-g-PAMPS复合水凝胶的制备及阳离子染料吸附性能[J].精细化工,2020,37(5):0

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  • 收稿日期:2019-10-17
  • 最后修改日期:2019-12-18
  • 录用日期:2019-12-28
  • 在线发布日期: 2020-03-23
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