有序介孔碳材料的模板化构筑及水处理应用研究
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陕西省教育厅专项科研计划项目(19JK0252),商洛市科技计划项目(SK2019-81)


Construction of ordered mesoporous carbon by templating method and its application research on water treatment
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    摘要:

    介孔碳材料是指孔径介于2 nm-50 nm的一类多孔碳材料。有序介孔碳材料,具有比表面积高、孔道结构规则有序、孔径分布狭窄、孔径大小可调控、表面易于修饰等结构特点和高机械强度、强吸附能力、化学惰性等性能特点,在诸多领域得到了广泛应用,特别是其作为新型吸附剂在水处理领域具有广阔的发展前景。有序介孔炭材料的制备方法主要有硬模板法和软模板法。模板和碳源的选择是控制有序介孔碳材料结构和性能的关键因素。本文从有序介孔硅、天然矿物、MOFs材料、嵌段共聚物等不同模板的角度对有序介孔碳、多级有序微/介孔碳、多级有序大/介孔碳的制备方法进行综述,并对有序介孔碳材料在水处理领域的应用进行简单介绍。

    Abstract:

    Mesoporous carbon materials are a kind of porous carbon materials with pore diameter between 2 nm and 50 nm. Ordered mesoporous carbon materials possess structural features such as high specific surface area, regular pore structure, narrow pore size distribution, controllable pore size and modifiable surface and performance characteristics such as high mechanical strength, strong adsorption ability and chemical inertness. These special structure and properties have made ordered mesoporous carbon widely used in many fields, especially as a new adsorbent in water treatment, which is a notable application direction with ecological and social value. Hard templating method and soft templating method are the main way to prepare ordered mesoporous carbon, and the selection of template and carbon precursor is crucial to the control of structure and properties. In this paper, the preparation methods of ordered mesoporous carbon, hierarchical ordered microporous/mesoporous carbon and hierarchical ordered macroporous/mesoporous carbon are reviewed from the perspectives of different templates such as ordered mesoporous silica, natural minerals, metal organic frameworks and block copolymers. Applications of ordered mesoporous carbon in water treatment are introduced including the removal efficiency, removal mechanism and modification effectiveness of ordered mesoporous carbon to heavy metal ion and organic pollutant.

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屈佳.有序介孔碳材料的模板化构筑及水处理应用研究[J].精细化工,2020,37(12):

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  • 收稿日期:2020-08-03
  • 最后修改日期:2020-09-29
  • 录用日期:2020-10-10
  • 在线发布日期: 2020-12-09
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