N-异丙基丙烯酰胺基智能膨润土制备及其性能
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TE254 TQ31TE39

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辽宁省教育厅基本科研项目


Preparation and properties of N-isopropylacrylamide-based smart bentonite
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Basic scientific research project of Liaoning Provincial Department of Education

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    摘要:

    以钠基膨润土为原料,通过硅烷偶联剂KH570的脱水缩合作用将N-异丙基丙烯酰胺(NIPAM)接枝在钠基膨润土表面,制备智能温敏膨润土(NIPAM-B)。采用单因素方法对NIPAM-B的合成指标进行优化,并利用XRD、FTIR技术对NIPAM-B进行表征,同时对NIPAM-B的温敏性、NIPAM-B悬浮液的流变性和悬浮性进行考察,并引入丙烯酸(AA)单体实现温度调控。结果表明,NIPAM-B具有良好的温敏特性,且该智能温敏膨润土悬浮液的流变性在40~60℃范围内表现出稳流特点以及升温增稠的特性。但该智能温敏膨润土相较于膨润土原土而言,悬浮性略有下降。此外,经过引入AA的温度调控作用,发现AA与NIPAM的添加量的物质的量比值每增加10%,智能温敏膨润土的LCST将提高10℃左右。

    Abstract:

    Using sodium bentonite as raw material, N-isopropyl acrylamide (NIPAM) is grafted on the surface of sodium bentonite through the dehydration condensation of silane coupling agent KH570 to prepare intelligent temperature-sensitive bentonite (NIPAM-B). The single-factor method was used to optimize the synthesis index of NIPAM-B, and XRD and FTIR technology were used to characterize NIPAM-B. At the same time, the temperature sensitivity of NIPAM-B and the rheology and suspension of NIPAM-B suspension were investigated. , And introduce acrylic acid (AA) monomer to realize temperature control. The results show that NIPAM-B has good temperature-sensitive characteristics, and the rheological properties of the intelligent temperature-sensitive bentonite suspension show steady flow characteristics and heating and thickening characteristics in the range of 40-60℃. However, the suspensibility of this smart temperature-sensitive bentonite is slightly lower than that of the original bentonite. In addition, after introducing the temperature control effect of AA, it is found that for every 10% increase in the ratio of the added amount of AA to NIPAM, the LCST of the smart temperature-sensitive bentonite will increase by about 10°C.

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潘一,徐明磊,詹倩茹,侯冰,杨双春,李宁. N-异丙基丙烯酰胺基智能膨润土制备及其性能[J].精细化工,2021,38(10):

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  • 收稿日期:2021-06-15
  • 最后修改日期:2021-06-26
  • 录用日期:2021-06-28
  • 在线发布日期: 2021-09-13
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