耐高温清洁压裂液的制备及性能评价
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TE39

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四川省杰出青年基金(2019JDJQ0047)


Preparation and evaluation of high-temperature resistant clean fracturing fluid
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Sichuan Province Fund for Distinguished Young Scholars (2019JDJQ0047)

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    摘要:

    以丙烯腈、二乙醇胺和芥酸为原料合成了芥酸酰胺丙基二羟乙基叔胺(UC22-OH),通过FTIR、1H NMR、13C NMR及HPLC-MS对其进行了结构表征。将UC22-OH用作稠化剂,配制耐高温清洁压裂液,考察温度对清洁压裂液表观黏度的影响,并探究高温下胶束聚集体的类型和尺寸。通过室内实验,对UC22-OH清洁压裂液体系的流变性、携砂性、破胶返排性以及地层伤害性进行了评价。结果表明,质量分数为4%的UC22-OH清洁压裂液体系,在120 ℃、170 s-1下剪切1.5 h,表观黏度稳定保持在65 mPa·s,说明UC22-OH清洁压裂液具有优异的耐温性和抗剪切性;在80 ℃下,该清洁压裂液体系的弹性模量G'>4.2 Pa,黏性模量G''>1.7 Pa;在陶粒体积分数为20%的情况下,可稳定携砂2 h,且该体系遇煤油后70 min之内彻底破胶,破胶液的表界面张力较低,说明该清洁压裂液体系在80 ℃下的携砂性能和破胶返排性能优异;在地层伤害性评价实验中,对比3种压裂液体系发现UC22-OH压裂液体系的渗透率损害率最低,仅为9.1%。通过对比压裂液的各项性能指标,发现UC22-OH清洁压裂液具有耐高温、低残渣、低伤害性、稳定携砂以及易破胶返排的优点。

    Abstract:

    Thickener (Z)-N-{3-[bis(2-hydroxyethyl)amino]propyl}docos-13-enamide (UC22-OH) for fracturing was synthesized from acrylonitrile, diethanolamine and erucic acid. Its chemical structure was characterized by 1H NMR, 13C NMR and HPLC-MS, which proves that the product was consistent with the target product. The effect of temperature on the apparent viscosity of fracturing fluid was studied, and the type and size of micelle aggregates at high temperature were analyzed. The rheology, sand-carrying, gel breaking and formation damage performance of the UC22-OH system were evaluated. The results showed that the clean fracturing fluid system was with a mass fraction of 4% UC22-OH, its apparent viscosity maintains 65 mPa·s under a shear rate of 170 s-1 at 120 ℃ for 1.5 h, indicating that UC22-OH clean fracturing fluid has excellent temperature resistance and shear resistance performance. At 80 ℃, the values of the elastic and viscous modulus (G' and G'') of the clean fracturing fluid system are >4.2 Pa and >1.7 Pa respectively. When the sand content is 20%, it can stably suspend sand within 2 h at 80 ℃. The system was completely broken within 70 minutes after encountering kerosene, and the surface interfacial tension value of the micelle-breaking fluid is low, which shows that the fracturing fluid system has excellent sand-carrying performance and micelle-breaking flowback performance at 80 °C; In the formation damage evaluation experiment, comparing the three fracturing fluid systems, the UC22-OH fracturing fluid system had the lowest permeability damage rate, only 9.1%. By comparing various performance indexes of fracturing fluid, it was found that UC22-OH clean fracturing fluid had the advantages of high temperature resistance, low residue, low damage, stable sand carrying, and easy flow interruption.

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熊利军,王犁,吴洋,鲁红升.耐高温清洁压裂液的制备及性能评价[J].精细化工,2022,39(1):

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  • 收稿日期:2021-07-06
  • 最后修改日期:2021-09-30
  • 录用日期:2021-09-30
  • 在线发布日期: 2022-01-11
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