一种长封固段固井用缓凝剂的制备及性能评价
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四川省区域创新合作项目(2021YFQ0045);油气藏地质及开发工程国家重点实验室(西南石油大学)资助项目(PLN2020-17)


Preparation and performance evaluation of a retarder used in long cementing interval
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Research and application of in-situ toughened cement for horizontal shale gas well cementing

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    摘要:

    针对目前常用缓凝剂存在的易引起油气井固井水泥浆异常胶凝、长封固段井中顶部水泥石强度发展缓慢等问题,本文通过硼酸与共沉淀法制备的镁铝型层状双氢氧化物(Mg/Al-CO3-LDH)进行离子交换反应合成了一种层状复合缓凝剂材料——硼酸根插层水滑石(Mg/Al-BA-LDH)。采用XRD、FTIR、SEM等对其结构进行表征。结果表明,制备的Mg/Al-BA-LDH结晶度较好,在pH=4.5下其层间距最大,为0.92nm。评价了添加Mg/Al-BA-LDH的水泥浆体系的综合性能。结果表明,Mg/Al-BA-LDH在90~170℃下能有效调节水泥浆稠化时间,其稠化曲线平稳且呈直角稠化。含Mg/Al-BA-LDH的水泥石24h低温强度大于14MPa,掺量为0.5%(掺量以水泥质量为基准)时,其7d强度可达33.97MPa。在不同的温差条件下养护后其顶部水泥石抗压强度正常发展,满足长封固段固井施工要求,Mg/Al-BA-LDH的填充效应以及晶体效应在水泥水化后期中起主导作用,促进水泥的水化,有效的缓解了因缓凝作用而导致的浆体抗压强度下降。

    Abstract:

    A type of layered composite retarder, boric acid root intercalated hydrotalcite(Mg/Al-BA-LDH)was synthesized by ion exchange reaction between boric acid and magnesium aluminum lamellar dihydroxides(Mg/Al-CO3-LDH)which was prepared by coprecipitation method ,in order to well overcome the problems of abnormal cementing slurry and the strength of the cement paste developing slowly at the top of the long-sealing section cementing of the commonly used retarders.The structure was characterized by XRD、FTIR and SEM,results show that the prepared Mg/Al-BA-LDH has a good crystallite, and the interlayer spacing is 0.92nm at pH=4.5.At the same time,the comprehensive performance of the cement slurry system with Mg/Al-BA-LDH was evaluated.The experimental results show that the retarder can effectively adjust the thickening time of the cement slurry at 90 ℃~170℃,and the thickening curve is stable, indicating right-angle thickening.The compressive strength of cement stone containing Mg/Al-BA-LDH was greater than 14MPa at low temperature for 24h, and the strength can reach 33.97mpa after 7d when the content is 0.5%( Dosage is based on cement quality).After curing under different temperature difference conditions, the compressive strength of the top cement stone develops normally and meets the construction requirements, which could be applied to long sealing and large temperature range cementing operation. The filling of hydrotalcum material and the crystal effect played a leading role in the process of cement hydration, thus promoting cement hydration and effectively alleviating the slurry compressive strength decline caused by retarding effect.

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左天鹏,程小伟,吴昊,刘芃,张春梅,刘开强,黄盛.一种长封固段固井用缓凝剂的制备及性能评价[J].精细化工,2022,39(3):0

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  • 收稿日期:2021-07-11
  • 最后修改日期:2021-12-03
  • 录用日期:2021-12-06
  • 在线发布日期: 2022-01-11
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