吉木萨尔页岩油乳化原因及对策
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中石油战略合作科技专项


Causes and Countermeasures of shale oil emulsification in jimusar
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PetroChina strategic cooperation science and technology project;

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    摘要:

    吉木萨尔原油压裂开采过程中乳化常出现乳化增黏现象,影响了原油正常生产。为明晰原油乳化原因,研究了原油组分、压裂液组分与pH等对乳状液稳定性和对界面性质的影响;采用醇碱萃取得到石油酸,通过高分辨质谱分析了石油酸分布和组成。结果表明,胍胶压裂液体系相较于聚合物压裂液体系更易乳化。引起吉木萨尔原油乳化的主要原因:一是原油中含有较多的环烷酸、芳香酸、脂肪酸等界面活性物质;二是压裂液组分中的碱及弱碱性地层水与原油中的酸性物质长时间作用,形成界面活性较强的皂类;三是在生产过程中强烈的搅拌,促进原油乳化。为解决乳化增黏问题,在原油与压裂液混合液中加入0.5%JN-1降黏减阻剂后,30℃时混合液黏度降由2232 mPa·s低至155mPa·s,可有效降低混合液黏度。针对吉木萨尔页岩油乳化问题,建议采用不含碱的滑溜水体系压裂开发,并且在压裂液中加入降黏剂,是解决吉木萨尔原油压裂后乳化增黏的有效方法之一。

    Abstract:

    Emulsification and viscosity increase often occur during fracturing production of jimusar crude oil, which affects the normal production of crude oil. In order to clarify the cause of crude oil emulsification, the effects of crude oil composition, fracturing fluid composition and pH on emulsion stability and interface properties were studied; Petroleum acid was obtained by alcohol alkali extraction. The distribution and composition of petroleum acid were analyzed by high resolution mass spectrometry. The results show that guanidine gum fracturing fluid system is more emulsified than polymer fracturing fluid system. The main reasons for the emulsification of jimusar crude oil are as follows: first, there are many interfacial active substances such as naphthenic acid, aromatic acid and fatty acid in the crude oil; Second, the alkali and weakly alkaline formation water in the fracturing fluid components interact with the acidic substances in the crude oil for a long time to form soaps with strong interfacial activity; Third, strong stirring in the production process to promote crude oil emulsification. In order to solve the problem of emulsification and viscosity increasing, after adding 0.5% JN-1 viscosity reducing and drag reducing agent to the mixture of crude oil and fracturing fluid, the viscosity of the mixture decreases from 2232 mPa·s to 155 mPa·s at 30 ℃, which can effectively reduce the viscosity of the mixture. In view of the emulsification problem of jimusar shale oil, it is suggested to adopt alkali free sliding water system for fracturing development, and add viscosity reducer to the fracturing fluid, which is one of the effective methods to solve the emulsification and viscosity increase of jimusar crude oil after fracturing.

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郑苗,高晨豪,张凤娟,许振芳,张敬春,郭继香.吉木萨尔页岩油乳化原因及对策[J].精细化工,2022,39(2):

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  • 收稿日期:2021-08-05
  • 最后修改日期:2021-10-11
  • 录用日期:2021-10-13
  • 在线发布日期: 2022-01-11
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