聚合物基镁离子固态电解质的研究进展Q
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O646;TM911

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国家自然科学基金项目(面上项目,重点项目,重大项目)


Research progress of polymer-based magnesium ion solid electrolyte
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The National Natural Science Foundation of China (General Program, Key Program, Major Research Plan)

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    摘要:

    摘要:镁离子电池因其比容量高、资源丰富、环境友好、安全性高(无枝晶)等优势,在储能电池领域脱颖而出。然而,镁金属负极在液态电解质中易钝化导致其电化学性能不佳。因此,开发高效适用的固态电解质对实现高性能实用化镁离子电池至关重要。近年来,以聚合物为基底的镁离子固态电解质得到快速发展。本文综述了国内外聚合物基镁离子固态电解质的离子电导率、解决镁金属负极钝化效应的贡献及应用于镁离子电池的研究进展。聚合物电解质具有优异的机械稳定性、电化学稳定性、热稳定性且离子电导率高、成本低。但由于镁离子较高的电荷密度和较强的溶剂化作用,限制了其在固态电解质中的解离与扩散。此外,聚合物固态电解质仍不能完全解决镁金属表面钝化问题。本文可使研究人员快速掌握当前镁离子固态电解质研究中面临的挑战以及可行的解决方案,为镁离子电池用固态电解质的研制提供参考。

    Abstract:

    Abstract: Magnesium-ion batteries emerge as a promising candidate in the energy storage field because of its high specific capacity, rich resources, environmental friendliness and excellent safety (dendrite-free). However, the magnesium metal anode is easily passivated in the liquid electrolyte, resulting in the poor electrochemical performance. Therefore, developing highly efficient and applicable solid electrolytes is essential for the realization of high-performance and practical magnesium ion batteries. In recent years, polymer based solid electrolytes have been rapidly developed. This article reviews the ionic conductivity of polymer-based magnesium ion solid electrolytes at home and abroad, the contribution to solving the passivation effect of magnesium metal anodes, and the research progress of its application in magnesium ion batteries. This article summarizes recent advance in polymer-based magnesium ion solid electrolyte, in terms of ionic conductivity, contribution to solving the magnesium anode passivation and application in Mg-ion batteries. Polymer electrolyte has excellent mechanical/electrochemical/thermal stability, high ionic conductivity, and low cost. However, the high charge density and strong solvation of magnesium ions limit its dissociation and diffusion in solid electrolytes. Also, the surface passivation issue of Mg metal anode has not been fully addressed in polymer-based solid electrolyte. This review will enable researchers to quickly grasp the current challenges and feasible solutions in the research of solid magnesium ion electrolytes, and provide guidance for the development of electrolytes in the future.

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费贵强,孙丽丽,舒珂维,王海花.聚合物基镁离子固态电解质的研究进展Q[J].精细化工,2022,39(2):

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  • 收稿日期:2021-08-13
  • 最后修改日期:2021-11-10
  • 录用日期:2021-11-11
  • 在线发布日期: 2022-01-11
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