水性超支化环氧树脂的合成及应用
DOI:
CSTR:
作者:
作者单位:

作者简介:

通讯作者:

中图分类号:

TS761.6

基金项目:


Synthesis and application of wateborne hyperbranched epoxy resin
Author:
Affiliation:

Fund Project:

  • 摘要
  • |
  • 图/表
  • |
  • 访问统计
  • |
  • 参考文献
  • |
  • 相似文献
  • |
  • 引证文献
  • |
  • 资源附件
  • |
  • 文章评论
    摘要:

    以丙三醇三缩水甘油醚和二甘醇为原料,合成了水性超支化环氧树脂HE-32。以己二酸和二乙烯三胺为原料,合成了水性聚酰胺PA236,将其接枝到HE-32上得到改性水性聚酰胺PA236G。向PA236G水溶液中加入其质量2%~4%的水性固化剂906得到粘缸剂CA-21。采用1HNMR、13CNMR、FTIR、GPC对HE-32、PA236和PA236G进行了表征,使用热重分析测试了3种产物的热性能,对CA-21进行了薄膜性能和力学性能的测试。结果表明,聚合物被成功合成,且PA236已成功接枝到HE-32上。PA236G的热稳定性大幅提高,CA-21的平均剪切强度可达0.17 MPa,对基材的附着力可达171.16 N,具有作为粘缸剂使用的潜力。

    Abstract:

    In this study, the waterborne hyperbranched epoxy resin (HE-32) is synthesized using glycerol triglycidyl ether and diethylene glycol , the waterborne polyamide (PA236) is synthesized using adipic acid and diethylene triamine, then graft PA236 onto HE-32 to get modified waterborne polyamide PA236G, finally, 2~4% waterborne curing agent is added to obtain the creping adhesive CA-21. The analysis of HE-32, PA236 and PA236G using 1H-NMR, 13C-NMR, FTIR and GPC confirmed that the polymer was successfully synthesized and PA236 was successfully grafted onto HE-32; The thermal properties of the three products have been tested by thermogravimetric analysis, and the thermal stability of PA236G has been greatly improved. Finally, the film performance and mechanical properties of CA-21 were tested. The results showed that the average shear strength of CA-21 can reach 0.17 MPa, and the adhesion to the substrate can reach 171.16 N, which proved it has the potential to be used as a viscous agent.

    参考文献
    相似文献
    引证文献
引用本文

李帅,张坤,王义刚,陈洁,聂小安.水性超支化环氧树脂的合成及应用[J].精细化工,2022,39(3):

复制
分享
文章指标
  • 点击次数:
  • 下载次数:
  • HTML阅读次数:
  • 引用次数:
历史
  • 收稿日期:2021-08-24
  • 最后修改日期:2021-11-28
  • 录用日期:2021-11-30
  • 在线发布日期: 2022-01-29
  • 出版日期:
文章二维码