一种耐超高温、耐酸聚合物的制备及性能测试
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TE357

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Preparation and performance test of an ultra-high temperature and acid resistant polymer
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    摘要:

    摘要:为解决常规聚合物无法满足超高温深井酸化压裂的技术要求,本文分别以丙烯酰胺(AM) 甲基丙烯酰氧乙基三甲基氯化铵(DMC)、AM DMC SMA(十八烷基甲基丙烯酸酯)为原料,通过自由基聚合制备出两种耐酸聚合物SY-1和SY-2,并对其结构进行表征及性能测试。结果表明:SY-2红外谱图中720 cm-1为—(CH2)n—的弯曲振动吸收峰,单体成功接枝到聚丙烯酰胺分子链上;热重分析表明,SY-1升温至600℃失重比为98%,SY-2失重比86%,热稳定性得到改善;质量分数为20%盐酸中,SY-2质量分数0.8%:180℃,170s-1流变性能测试,SY-2剪切终点黏度56mPa?s,90℃、120℃、150℃剪切1h,黏度为83.6mPa?s、43.5mPa?s、27.8mPa?s,剪切稳定性分别为85.66%、74.45%、52.01%; 180℃、3MPa条件下,静态酸岩反应速率为8.94?10-5(g/cm2?s),较常规SY-1反应速率1.69?10-4(g/cm2?s)减小一个量级。且与缓蚀剂、铁离子稳定剂配伍性良好,克服高温酸化压裂技术的应用瓶颈。

    Abstract:

    In order to solve the problem that conventional polymers cannot meet the technical requirements of acid fracturing in ultra-high temperature and deep wells, two polymers SY-1 and SY-2 were prepared by free radical polymerization using acrylamide(AM) 2-trimethylammonium ethyl methacrylate chloride (DMC)and AM DMC SMA ( octadecyl methacrylate ) as raw materials, and their structures were characterized and their properties were tested. The results showed that 720 cm-1in SY-2 infrared spectrum was the bending vibration absorption peak of—(CH2)n—, and the monomer was successfully grafted onto the polyacrylamide molecular chain. Thermogravimetric analysis showed that the weight loss ratio of SY-1 to 600?Cwas 98%, and that of SY-2 was 86%, and the thermal stability was improved. In 20% hydrochloric acid, the mass fraction of SY-2 is 0.8%: 180?C, 170s-1 rheological properties test, SY-2 shear end viscosity 56mPa?s, 90?C, 120?C, 150?C shear 1h, viscosity 83.6mPa?s, 43.5mPa?s, 27.8mPa?s, shear stability were 85.66%, 74.45%, 52.01%. At 180?C and 3 MPa, the static acid-rock reaction rate is 8.94 ? 10-5 (g/cm2 ? s), which is one order of magnitude lower than the conventional SY-1 reaction rate of 1.69 ? 10-4 (g/cm2 ? s). It has good compatibility with corrosion inhibitor and iron ion stabilizer to overcome the application bottleneck of high temperature acid fracturing technology.

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李朋,赖小娟,王磊,李鹏,高进浩,张小鑫.一种耐超高温、耐酸聚合物的制备及性能测试[J].精细化工,2022,39(2):0

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  • 收稿日期:2021-09-11
  • 最后修改日期:2021-12-13
  • 录用日期:2021-12-21
  • 在线发布日期: 2022-01-11
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