木质素催化氧化制备芳香醛研究进展
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国家自然科学基金项目(面上项目,重点项目,重大项目)


Research progress in the preparation of aromatic aldehydes by catalytic oxidation of lignin
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The National Natural Science Foundation of China (General Program, Key Program, Major Research Plan)

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    摘要:

    催化氧化技术是实现木质素资源化利用的有效途径之一,可将木质素转化为具有高度官能化的芳香醛(对羟基苯甲醛、香草醛、紫丁香醛等)。芳香醛是合成染料、香料及药品的重要中间体,具有较大的工业应用价值。于此,本文综述了国内外有关木质素在金属催化氧化、有机催化氧化、电化学催化氧化、光催化氧化和离子液体催化氧化等方面制备芳香醛的最新研究进展,并对不同催化体系下反应过程机理进行了简要阐述。在此基础上,展望了有关木质素催化氧化增值的研究方向,对不同木质素应研发具有针对性的催化剂,以便有助于实现木质素高值化利用。最后,指出调控金属氧化物的表面氧空位是一种选择性催化木质素制备芳香醛的有效策略。

    Abstract:

    Catalytic oxidation technique is one of effective ways to realize resource utilization of lignin, which can transform lignin into aromatic aldehydes (p-hydroxybenzaldehyde, vanillin, syringaldehyde, etc.) with high functionalization. Aromatic aldehydes are important intermediates in the synthetic of dyes, perfumes and pharmaceuticals, and have great industrial application value. Herein, this review summarizes the latest research progress in the preparation of aromatic aldehydes from lignin at home and abroad through five aspects: metal catalytic oxidation, organic catalytic oxidation, electrochemical catalytic oxidation, photocatalytic oxidation and ionic liquids catalytic oxidation, and briefly elaborates the reaction process mechanism under different catalytic systems. On this basis, the direction of research regarding the value-added of lignin catalytic oxidation is prospected to develop targeted catalysts for different lignin in order to contribute to the high value utilization of lignin. Finally, it is pointed out that regulating the oxygen vacancy on the surface of metal oxides is an effective strategy to selectively catalyze the preparation of aromatic aldehydes from lignin.

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周姚红,张晓华,熊万明.木质素催化氧化制备芳香醛研究进展[J].精细化工,2022,39(3):

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  • 收稿日期:2021-09-27
  • 最后修改日期:2021-12-06
  • 录用日期:2021-12-07
  • 在线发布日期: 2022-01-11
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