轻质高强芳纶纳米纤维/聚酰亚胺复合气凝胶的制备及性能
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TQ323.7

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国家自然科学基金项目(面上项目,重点项目,重大项目)


Fabrication and Properties of Robust ANFs/Polyimide Composites Aerogel
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The National Natural Science Foundation of China (General Program, Key Program, Major Research Plan)

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    摘要:

    聚酰亚胺 (PI) 因其优异的综合性能备受关注,将其构建成高强度气凝胶对拓展其在航空航天、微电子等高科技领域的应用具有重要意义。本文以4,4’-二氨基二苯醚 (ODA) 和3,3’,4,4’-二苯甲酮四羧酸二酐 (BTDA) 为单体构筑聚酰亚胺气凝胶,通过引入芳纶纳米纤维(ANFs)对气凝胶进行骨架增强,并通过傅立叶红外光谱(FT-IR)、扫描电子显微镜(SEM)等探究了ANFs对气凝胶化学结构、微观形貌以及力学性能等的影响。研究表明,ANFs通过氢键作用与前驱体聚酰胺酸(PAA)结合,并均匀分散在气凝胶骨架中,从而对其进行有效增强。引入ANFs后,气凝胶制备过程中的体积收缩率有效降低,当ANFs添加量增加至PAA的4 wt% 时,气凝胶体积收缩率由63% 降低至54%;与PI气凝胶相比,添加4 wt% ANFs复合气凝胶的杨氏模量由1.8 MPa提升至6.9 MPa,压缩回弹率提升了37%。

    Abstract:

    Polyimide (PI) has attracted much attention due to its excellent comprehensive properties. The construction of high-strength aerogels by PI is of great significance for expanding its applications in high-tech fields such as aerospace, microelectronics, etc. In this work, 4,4'-oxydianiline (ODA) and 3,3',4,4'-benzophenone tetracarboxylic dianhydride (BTDA) were used as monomers to construct polyimide aerogels, and aramid nano fibers (ANFs) were introduced to enhance the skeleton of aerogels. The influences of ANFs on the chemical structure, microscopic morphology and mechanical properties of aerogels were explored through Fourier Infrared Spectroscopy (FT-IR) and Scanning Electron Microscopy (SEM). The results revealed that ANFs were combined with the precursor polyamic acid (PAA) through hydrogen bonding, and were evenly dispersed to enhance the aerogel skeleton effectively. It’s clear that the volume shrinkage rate during the aerogel preparation process effectively reduced with the introduction of ANFs. Compare to the pure PI aerogels, the volume shrinkage of aerogels with 4 wt% ANFs is reduced from 63% to 54%, the Young’s modulus increased from 1.8 MPa to 6.9 MPa, and the compression rebound rate increased by 37%.

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卓龙海.轻质高强芳纶纳米纤维/聚酰亚胺复合气凝胶的制备及性能[J].精细化工,2022,39(3):

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  • 收稿日期:2021-09-28
  • 最后修改日期:2021-11-05
  • 录用日期:2021-11-08
  • 在线发布日期: 2022-01-29
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