乙氧基化咪唑啉阻锈剂的制备及性能研究
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TG174.42

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辽宁省教育厅自然科学青年基金(LQGD2020019)


Study on the preparation and performance of ethoxylated imidazoline rust inhibitor
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Natural Science Youth Fund of the Education Department of Liaoning Province(LQGD2020019)

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    摘要:

    以油酸和羟乙基乙二胺为原料,经酰胺化、环化反应生成咪唑啉中间体,再加成聚合环氧乙烷,得到乙氧基化咪唑啉阻锈剂。通过失重法、盐水浸渍法、盐水浸烘实验、电化学综合实验和扫描电镜等方法评价该阻锈剂对Q235碳钢在3.5%NaCl的饱和Ca(OH)2溶液的阻锈性能,并通过水泥净浆流动性实验,测试该阻锈剂对混凝土流动性的影响。研究结果表明,该阻锈剂在3.5%NaCl的饱和Ca(OH)2腐蚀介质中能有效的保护Q235碳钢免遭腐蚀,通过电化学实验,证明该阻锈剂是以抑制阳极反应为主的混合型阻锈剂,当质量浓度为4%时,钢筋的阻锈效率达到99.13%,扫描电镜显示碳钢表面光滑平整。水泥净浆流动性实验结果表明该阻锈剂对混凝土流动性无明显不利影响。

    Abstract:

    Using oleic acid and hydroxy ethyl ethylene diamine as raw materials, an imidazoline intermediate is generated through amidation and cyclization reactions, and then ethylene oxide is added to polymerize to obtain an ethoxylated imidazoline rust inhibitor. The corrosion inhibition performance of this rust inhibitor on Q235 carbon steel in 3.5% NaCl saturated Ca(OH) 2 was evaluated by weight loss method, salt water immersion method, salt water immersion drying experiment, electrochemical comprehensive experiment and scanning electron microscope, and through the cement paste fluidity experiment, tested the influence of the rust inhibitor on the concrete fluidity.The research results show that the rust inhibitor can effectively protect Q235 carbon steel from corrosion in 3.5% NaCl saturated Ca(OH)2 corrosive medium. Through electrochemical experiments, it proves that the rust inhibitor is a mixed type rust inhibitor that mainly inhabits the anode reaction. When the mass concentration is 4%, the corrosion inhibition efficiency of the steel bar reaches 99.13%, and the scanning electron microscope shows that the surface of the carbon steel is smooth and flat. The experimental results of cement paste fluidity show that the rust inhibitor has no obvious adverse effect on the fluidity of concrete.

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杨振声,杨健,张晓娟,王冰.乙氧基化咪唑啉阻锈剂的制备及性能研究[J].精细化工,2022,39(4):

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  • 收稿日期:2021-11-16
  • 最后修改日期:2022-01-15
  • 录用日期:2022-01-17
  • 在线发布日期: 2022-01-29
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