温敏光子晶体及自适应结构色迷彩器件制备
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大连理工大学

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国家自然科学基金(22078048);大连高水平人才创新支持计划(2019RD06)


Self-adaptive photonic crystal structure color device and its application in camouflage field
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Dalian University of Technology

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National Natural Science Foundation of China (22078048); Dalian high level talent innovation support plan (2019rd06)

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    摘要:

    摘要:为制备出能够快速显示与环境匹配的色彩图案的器件,达到自适应环境的目的。以N,N-二甲基十二烷基氧化胺(C12DMHO)为基本单元,将N-异丙基丙烯酰胺(NIPAM)、双丙酮丙烯酰胺(DMAA)、丙烯酰胺(AM)在紫外聚合的条件下形成PNIPAM-co-PDAAM-co-PAM交联网络,制备了一种快速响应的C12DMAO/PNIPAM-co-PDAAM-co-PAM温敏型光子晶体水凝胶。通过包覆后与集成电加热板复合,构建自适应结构色器件。通过反色光谱测试、红外成像测试得出:通过将上述可聚合单体NIPAM、DMAA、AM比例的调整,材料的响应温度可在0~80 ℃范围内调节。当材料中单体含量为PNIPAM 0.2 g、DMAA 0.2 g、AM 0.05 g、MBAA 50 mg,响应的温度范围为22~30 ℃,结构色可以快速、动态可逆的在可见光区变化。

    Abstract:

    Abstract: This paper aims to prepare a device that can quickly display the color pattern matching with the environment, so as to achieve the purpose of adaptive environment. Taking N,N-Dimethyldodecylamine oxide (C12DMHO) as the basic unit, the PNIPAM-co-PDAAM-co-PAM cross-linking network was formed under the condition of UV polymerization of N- isopropylacrylamide (NIPAM), diacetone acrylamide (DMAA) and acrylamide (AM), and a fast responsive C12DMHO/PNIPAM-co-PDAAM-co-PAM temperature sensitive photonic crystal hydrogel was prepared. After coating, it is combined with the integrated electric heating plate to construct an adaptive structural color device. Through the reverse color spectrum test and infrared imaging test, it is concluded that the response temperature of the material can be adjusted in the range of 0 ~ 80 ℃ by adjusting the proportion of the above polymerizable monomers NIPAM, DMAA and am. When the monomer content in the material is PNIPAM 0.2 g, DMAA 0.2 g, am 0.05 g and MBAA 50 mg, the response temperature range is 24-30 ℃, and the structural color can change rapidly, dynamically and reversibly in the visible light region.

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牛文斌.温敏光子晶体及自适应结构色迷彩器件制备[J].精细化工,2022,39(8):

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  • 收稿日期:2022-01-11
  • 最后修改日期:2022-03-06
  • 录用日期:2022-03-11
  • 在线发布日期: 2022-07-05
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