高耐盐型聚合物的制备及其流变性能
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1.陕西科技大学 中国轻工业轻化工助剂重点实验室;2.长庆油田分公司第三采油厂;3.西安长庆化工集团有限公司

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TE348

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Preparation and rheological properties of high salt-tolerant polymer
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1.Shaanxi University of Science and Technology China Key Laboratory of Light Chemical Auxiliaries for Light Industry,Xi'2.'3.an;4.The Third Oil Production Plant of Changqing Oilfield Branch;5.Xi '6.an Changqing Chemical Group Co,LTD,Xi '7.Shaanxi University of Science and Technology China Key Laboratory of Light Chemical Auxiliaries for Light Industry,Xi&8.amp;9.#39;10.&

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    摘要:

    以丙烯酰胺(AM)、丙烯酸(AA)、含双键谷氨酸螯合剂(CH-3)为原料,通过反相乳液聚合法制备一种聚丙烯酰胺类聚合物p(AM/AA/CH-3)。通过FTIR及1HNMR表征证明功能基团成功引入聚合产物中。SEM结果表明,聚合物与盐离子形成更加致密规则的结构 。粒度分布测试结果表明,聚合物粒径分布集中且均匀。流变性测试结果表明,聚合物在盐水中存在应力环;质量分数为0.8%的p(AM/AA/CH-3)聚合物水溶液 表现出较好的耐温性能;在质量浓度为20000 mg/L的NaCl和CaCl2溶液中,质量分数为0.8%的p(AM/AA/CH-3)聚合物溶液在140 ℃下剪切1 h后的黏度分别为70.53 mPa·s和53.84 mPa·s,体系具有良好的耐温耐剪切性。聚合物在盐溶液中表现为弹性体,由于聚合物分子间作用力大于分子内部作用力,因而形成更加致密复杂的空间网络结构,聚合物弹性增大。

    Abstract:

    Using acrylamide (AM), acrylic acid (AA), and glutamic acid chelating agent (CH-3) with double bonds as raw materials, a new type of polyacrylamide polymer p(AM/AA/CH-3) was synthesized by inverse emulsion polymerization. The functional groups were successfully introduced into the polymerization reaction by infrared spectroscopy and proton nuclear magnetic resonance spectroscopy. Scanning electron microscope test results show that the polymer and salt ions form a more compact and regular structure. Laser particle size distribution analyzer test showed that the polymer particle size distribution was concentrated and uniform. The rheological test results show that the polymer has a stress loop in brine. The p(AM/AA/CH-3) aqueous solution with a mass fraction of 0.8% showed good temperature resistance. In 20000 mg/L NaCl and CaCl2 solutions, the viscosity of p(AM/AA/CH-3) with a mass fraction of 0.8% after shearing at 140 ℃ for 1 h was 70.53 mPa·s and 53.84 mPa·s, respectively. The system has good temperature resistance and shear resistance. The polymer behaves as an elastomer in the salt solution. Since the intermolecular force of the polymer is greater than the intramolecular force, a denser and more complex spatial network structure is formed, and the elasticity of the polymer increases.

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张雯娟,王磊,王丽敏,曹红燕,赖小娟,文新,张小鑫,魏向阳.高耐盐型聚合物的制备及其流变性能[J].精细化工,2022,39(10):

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  • 收稿日期:2022-03-25
  • 最后修改日期:2022-06-08
  • 录用日期:2022-06-09
  • 在线发布日期: 2022-09-17
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