玉米淀粉/生物基碳点复合光转换薄膜的制备及性能
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南宁师范大学 化学与材料学院

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广西自然科学基金(2016GXNSFAA380203)


Preparation and Properties of Corn starch/Bio-based Carbon Dots Composite light-converting Films
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College of Chemistry and Materials, Nanning Normal University

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Supported by Natural Science Fund of Guangxi Province (2016GXNSFAA380203)

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    摘要:

    以壳聚糖(CS)、N-(2-羟乙基)-乙二胺和无水柠檬酸(CA)为主要原料,通过水热法合成了壳聚糖接枝柠檬酸碳点〔P(CS-g-CA)CDs〕。然后以玉米淀粉(CST)为基体材料,通过流延法制备了一系列不同P(CS-g-CA)CDs含量的玉米淀粉/壳聚糖基碳点复合光转换薄膜〔CST/P(CS-g-CA)CDs5、CST/P(CS-g-CA)CDs10、CST/P(CS-g-CA)CDs20〕。采用荧光光谱、万能试验机、接触角测量仪和土埋降解实验研究了复合薄膜的光学性能、力学性能、亲水性能和降解性能。结果表明,随着P(CS-g-CA)CDs含量的增加,该复合薄膜的拉伸强度先升高后降低,断裂伸长率整体呈现增加趋势;复合薄膜的接触角从37.5°提高到87.0°,复合薄膜亲水性能下降;纯玉米淀粉薄膜无荧光响应,CST/P(CS-g-CA)CDs20能将374 nm处紫外光区的光转换为459 nm的蓝色荧光,该复合薄膜具有蓝光转光性能;难水溶的碳点混入可以延缓纯玉米淀粉薄膜的降解,延长薄膜使用寿命,实现降解速率可调控。

    Abstract:

    Chitosan-grafted citric acid carbon dots〔P(CS-g-CA)CDs〕were synthesized by hydrothermal reaction method using chitosan (CS), N-(2-hydroxyethyl)-ethylenediamine and anhydrous citric acid (CA) as the main raw materials.Then a series of corn starch/chitosan-based carbon dot composite light-converting films〔CST/P(CS-g-CA)CDs5,CST/P(CS-g-CA)CDs10,CST/P(CS-g-CA)CDs20〕with different P(CS-g-CA)CDs contents were prepared by flow-delaying method using corn starch (CST) as the base material.The optical properties, mechanical properties, hydrophilic properties and degradation properties of the composite films were investigated by fluorescence spectroscopy, a universal testing machine, contact Angle measuring instrument and soil degradation test. The results showed that with the increase of P(CS-g-CA)CDs, the tensile strength of the composite films increased first and then decreased, and the elongation at break showed an increasing trend as a whole; the contact angle of the composite films increased from 37.5° to 87° and the hydrophilic properties of the composite films decreased. Pure corn starch film without fluorescence response, CST/P(CS-g-CA)CDs20 can convert light in the UV region at 374 nm to blue fluorescence at 459 nm, and the composite film has blue light conversion performance. Difficult water-soluble carbon dots blending can delay the degradation of pure corn starch film, prolong the film service life, and achieve adjustable degradation rate.

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徐振光,鲁诗言,李晓婷,于淑娟,刘乐平.玉米淀粉/生物基碳点复合光转换薄膜的制备及性能[J].精细化工,2023,40(3):

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  • 收稿日期:2022-06-17
  • 最后修改日期:2022-09-16
  • 录用日期:2022-09-17
  • 在线发布日期: 2023-02-17
  • 出版日期: 2022-09-30