二维手风琴状MXene/棕榈酸复合相变材料的制备及性能
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上海电力大学能源与机械工程学院

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TK124

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上海市科委科技攻关项目


Preparation and properties of two-dimensional accordion-like MXene/palmitic acid composite phase change materials
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College of Energy and Mechanical Engineering, Shanghai University of Electric Power

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Shanghai Science and Technology Commission Science and Technology Project

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    摘要:

    摘要:随着人们对环境保护的重视,太阳能的开发利用成为当前研究重点,而发展以相变材料(PCM)为基础的潜热储存技术是提高太阳能开发利用的重要措施之一。以二维过渡金属碳化物和/或碳氮化物(MXene)为支撑骨架,以棕榈酸(PA)为相变材料,通过熔融共混法制备MXene复合材料(PA/MXene),并对不同Mxene添加量的复合材料进行了结构表征和热性能分析。与纯棕榈酸相比,PA/MXene-20%〔MXene质量分数为20%(以PA/MXene复合材料的质量为基准)〕的吸光范围从200-263.2 nm增加到200-679.3 nm,降解温度提高了13%,导热能力可增加到200%,光热转换效率达到84.5%,可实现太阳能光热转换、热能储存的一体化应用。

    Abstract:

    With the emphasis on environmental protection, the development and utilization of solar energy has become the focus of current research, and the development of latent heat storage technology based on phase change materials (PCM) is one of the important measures to improve the development and utilization of solar energy. In this paper, MXene composites (PA/MXene) were prepared by melt blending method using two-dimensional transition metal carbide and/or carbon nitride (MXene) as the support skeleton and palmitic acid (PA) as the phase change material, and the composites with different Mxene additions were structurally characterized and thermally characterized. Compared with pure palmitic acid, the light absorption range of PA/MXene-20% [MXene mass fraction of 20% (based on the mass of PA/MXene composite)] is increased from 200-263.2 nm to 200-679.3 nm, the degradation temperature is increased by 13%, the thermal conductivity can be increased to 200%, and the photothermal conversion efficiency reaches 84.5%, which can realize integrated application of solar photothermal conversion and thermal energy storage.

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孟良晨,闫 霆,王 凯,汤 鑫,潘卫国.二维手风琴状MXene/棕榈酸复合相变材料的制备及性能[J].精细化工,2023,40(6):

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  • 收稿日期:2022-09-28
  • 最后修改日期:2022-12-06
  • 录用日期:2022-12-07
  • 在线发布日期: 2023-05-11
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