基于四重氢键的自修复温敏相变凝胶的制备及性能
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江南大学 机械工程学院

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TB34

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国家自然科学基金(51503084);中国博士后科学基金(2016M601713);江苏省博士后科学基金(1601068C)


Preparation and properties of temperature-sensitive phase change hydrogels based on quadruple hydrogen bond self-healing
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1.College of Mechanical Engineering, Jiangnan University, Wuxi 214122, Jiangsu, China;2.Jiangnan University

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National Natural Science Foundation of China (No. 51503084), China Postdoctoral Science Foundation (No. 2016M601713) and Postdoctoral Science Foundation of Jiangsu Province (No.1601068C)

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    摘要:

    为提高定型相变材料(SSPCM)的使用寿命,以水和离子液体(IL)为相变材料(PCM),N-异丙基丙烯酰胺(NIPAM)为单体,壳寡糖(COS)为添加剂,引入2-脲基-4[1H]-嘧啶酮(UPy)形成四重氢键二聚体,采用自由基聚合法制备了自修复温敏性相变凝胶(S-EBIL)。通过FTIR、SEM、TEM对相变凝胶的化学结构与微观形貌进行表征,并测定了相变凝胶的自修复性、溶胀性和热性能。结果表明,相变凝胶具有多孔结构,内部孔径为18~38 μm,微凝胶核壳尺寸2~4 μm。相变凝胶具有温度敏感性,当温度升高时,相变凝胶黏弹性增大,不仅能维持相变材料的基本形状,而且能防止相变材料泄漏。相变凝胶相变温度为-10~0 ℃,相变焓值最高为252.9 J/g,导热系数为0.52 W/(m?K)。自修复温敏相变凝胶(S-EBIL3,IL与H2O质量比为3∶10)修复效率可达95.5%(30 s)。

    Abstract:

    In order to improve the service life of the shape-stabilized phase change material (SSPCM), the self-healing temperature-sensitive phase change hydrogels were prepared by free radical polymerization method using water and ionic liquid (IL) as PCM, N-isopropylacrylamide as the monomer, and chitosan (COS) as an additive, and the introduction of 2-ureido-4[1H]-pyrimidinone (UPy) to form a quadruple hydrogen bonds dimer. The chemical structure and micromorphology of the phase change hydrogels were characterized by FTIR, SEM, and TEM, and self-healing, swelling, and thermal properties of the phase change hydrogels were also measured. The results showed that the phase change hydrogel had a porous structure. The internal pore size was 18~38 μm, and the microgel core-shell size was 2~4 μm. The phase change hydrogels showed temperature sensitivity. As the temperature increased, the viscoelasticity of the phase change hydrogel became stronger, which not only maintains the basic shape but also prevents the leakage of the phase change material. The phase change hydrogels had a phase change temperature range from -10 °C to 0 °C. The phase change enthalpy and thermal conductivity of phase change hydrogel could reach up to 252.9 J/g and 0.52 W/(m?K). The rheological experiment indicated that phase change hydrogel (S-EBIL3, the mass ratio of IL to H2O is 3∶10) had a self-healing efficiency of 95.5% within 30 s.

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陈小菁,丘晓琳,范晓月,刘华萱.基于四重氢键的自修复温敏相变凝胶的制备及性能[J].精细化工,2023,40(8):

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  • 收稿日期:2022-11-25
  • 最后修改日期:2023-01-26
  • 录用日期:2023-01-28
  • 在线发布日期: 2023-09-08
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