Efficient, clean and non-toxic and non-hazardous catalysts are the focus to realize the decomposition of formic acid (HCOOH) as chemical hydrogen storage material for hydrogen production. In this paper, TiO₂ carriers were prepared by hydrothermal method at 453 K, and then NiCl₂.6H₂O and K₂PdCl₄ metal solutions with a total amount of 0.1 mmol were added to them by impregnation method to synthesize NiPd/TiO₂ catalysts by loading the active components Ni and Pd onto TiO₂ carriers, and to investigate their effects on the performance of catalytic formic acid decomposition for hydrogen production. The results of the investigation showed that the reaction conversion frequency (TOF) value of the NiPd/TiO₂ catalyst was the largest when the metal Ni:Pd ratio was 2:8 under the catalysis of light, at which the TOF of the catalyst was 3528 h_-1^{, and the activation energy (}E_a) of formic acid decomposition on this catalyst was 53.9 kJ/mol.