螺吡喃类光致变色材料改性与应用进展
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1.南京理工大学;2.中国船舶集团有限公司第七二五研究所海洋腐蚀与防护全国重点实验室

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TQ630

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国家自然科学基金(51577093);2023年厦门市自然科学基金(3502Z202371042)


Advances in the modification and application of spiropyran-based photochromic materials
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1.Nanjing University of Science and Technology;2.State Key Laboratory for Marine Corrosion and Protection,Luoyang Ship Material Research Institute LSMRI

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    摘要:

    有机光致变色材料通过在紫外光与可见光照射下发生可逆的光异构化过程,进而实现颜色的变化。其中螺吡喃材料是一种性能优异的有机光致变色材料,其变色行为可通过多种条件控制,如光照、温度、pH、机械压力等。可将螺吡喃分子制备成光致变色聚合物、金属有机框架、微胶囊等多种材料,在光信息存储、智能传感器、防伪与加密、靶向药物、荧光探针等领域具有优良的应用与前景,备受研究者的关注与青睐。本文结合国内外最新研究进展,综述了螺吡喃材料的结构特性及其在各类复合材料中的应用,包括总结归纳螺吡喃类材料的制备合成和分子结构,分析螺吡喃材料改性设计与功能实现的联系,讨论各种光致变色螺吡喃材料的应用研究。最后,对螺吡喃材料未来发展方向进行了展望。

    Abstract:

    Organic photochromic molecules undergo reversible isomerization with UV and visible light to achieve color change. Spiropyran is an organic photochromic material with outstanding performance, and its color-changing behavior can be regulated under a variety of conditions, including light, temperature, pH, and mechanical pressure. Spiropyran molecules can be utilized to prepare photochromic polymers, MOFs, microcapsules, and other materials. These have important applications and prospects in optical information storage, smart sensors, anti-counterfeiting and encryption, targeted drugs, fluorescent probes, and more. Consequently, they have captured significant attention and interest from researchers. This mini review provides a comprehensive review of the structural properties of spiropyran materials and their applications in various composites. It summarizes the preparation, synthesis, and molecular structure of spiropyran materials, analyzes the linkage between the modification design of spiropyran materials and the realization of their functions, and discusses the latest domestic and international research progress and application studies of various photochromic spiropyran materials. Finally, it envisions the future development direction of spiropyran materials.

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刘同力,黄从树,王晶晶,梁宇,谢志鹏,庄海燕,李九龙,朱绪飞.螺吡喃类光致变色材料改性与应用进展[J].精细化工,2024,41(12):

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  • 收稿日期:2023-11-20
  • 最后修改日期:2024-01-31
  • 录用日期:2024-01-29
  • 在线发布日期: 2024-12-10
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