微凝胶增强聚丙烯酰胺水凝胶的制备及性能
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1.陕西科技大学 轻工科学与工程学院;2.长庆油田分公司油气工艺研究院

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国家自然科学基金委员会,面上项目(22378250);陕西省科学技术厅,陕西自然科学基础研究计划重点项目(特别支持)(2023JC-XJ-12); 陕西省创新能力支撑计划资助(2021TD-16)


Preparation and properties of microgel reinforced polyacrylamide hydrogels
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1.Shaanxi University of Science &2.amp;3.Technology,College of Bioresources Chemical and Materials Engineering;4.Shaanxi University of Science & Technology,College of Bioresources Chemical and Materials Engineering;5.Oil & Gas Technology Research Institute, Changqing Oilfield Company

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    摘要:

    以2-丙烯酰胺-2-甲基丙磺酸(AMPS)、丙烯酰胺(AM)等为单体,通过原位自由基聚合和机械破碎法制备了微凝胶(MG)悬浮液,进而将其与丙烯酰胺(AM)溶液复合,通过引发聚合制备了微凝胶增强聚丙烯酰胺(MG-PAM)水凝胶。采用FTIR、SEM对水凝胶结构、形貌进行了表征,并对其力学性能、溶胀性能和能量耗散性能进行了测定。结果表明:MG悬浮液用量为40 %时,水凝胶的压缩强度可达25.42 MPa (95 %形变),拉伸强度和断裂伸长率分别可达201.2 KPa和405.4 %,在不同应变(70%、80%)下均具有良好的能量耗散性能,该水凝胶还可以承受不同的机械变形,具有优异的力学性能。

    Abstract:

    Microgel (MG) suspension was prepared using 2-acrylamide-2-methylpropanesulfonic acid (AMPS) and acrylamide (AM) as monomers by in-situ radical polymerization and mechanical crushing, and then the microgel reinforced polyacrylamide (MG-PAM) hydrogel was prepared by triggering polymerization with acrylamide (AM) solution. The structure and morphology of the hydrogel were characterized by FTIR and SEM, and its mechanical properties, swelling properties and energy dissipation properties were measured. The results show that: When the dosage of MG suspension is 40%, the compressive strength of the hydrogel can reach 25.42MPa (95% deformation), the tensile strength and the elongation at break can reach 201.2 KPa and 405.4 % respectively, and the hydrogel has good energy dissipation performance under different strains (70%, 80%). The hydrogel can also withstand different mechanical deformation. It has excellent mechanical properties.

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吕斌,张永刚,吕宝强,高党鸽,任静静,马建中.微凝胶增强聚丙烯酰胺水凝胶的制备及性能[J].精细化工,2024,41(12):

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  • 收稿日期:2023-12-29
  • 最后修改日期:2024-03-05
  • 录用日期:2024-02-07
  • 在线发布日期: 2024-12-10
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