水性光油用软硬硅丙复合乳液的制备及其耐高温性能影响
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陕西科技大学 化学化工学院

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TQ628.5

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国家自然科学(22078189);陕西省教育厅产业化项目(19jC010);陕西省特支计划—科技创新人才项目;陕西省重点研发项目(2020GY-243)


Preparation of soft and hard silicon-propylene composite emulsion for water-based varnish and its influence on high temperature resistance
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College of Chemistry and Chemical Engineering,Shaanxi University of Science and Technology,Xi''an

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    摘要:

    为改善水性光油耐热性能和涂层附着力,以丙烯酸丁酯(BA)、甲基丙烯酸甲酯(MMA)分别为软、硬单体进行乳液粒子设计,通过调整BA、MMA添加比例制备具有不同玻璃化转变温度(Tg)值的低Tg、高Tg丙烯酸酯乳液,以γ-甲基丙烯酰氧基丙基三甲氧基硅烷(KH570)为交联单体改性丙烯酸酯乳液制备低Tg、高Tg硅丙乳液,进一步采用软、硬乳液复配的方式制备复配乳液,最后将低Tg、高Tg硅丙乳液和复配乳液作为水性光油连接料制备水性光油。基于SEM、TGA、DSC、拉伸实验等,考察了KH570用量(以聚合单体总质量为基准的质量百分数,下同)对软、硬硅丙乳液以及水性光油的性能影响。结果表明,KH570用量为3%制备的低Tg硅丙乳液(dSiPA-3)的平均粒径为116.5 nm,最低成膜温度(MFT)为16.6 ℃,乳胶膜的水接触角为68.6°,Tg=14.25 ℃,水性光油耐水次数高达50次,涂层附着力为0级,耐高温抗粘连可达到150 ℃;dSiPA-3与高Tg硅丙乳液(gSiPA-3)以质量比0.8∶1的比例复配时,复配乳液的MFT为33.8 ℃,乳胶膜的Tg为14.19和63.54 ℃,水接触角为77.9°,水性光油耐摩擦500次,耐水50次,耐高温抗粘连温度可达到210 ℃,涂层附着力0级。

    Abstract:

    In order to improve the heat resistance and coating adhesion of waterborne varnish, butyl acrylate (BA) and methyl methacrylate (MMA) were used to design emulsion particles for soft and hard monomers, respectively, low Tg and high Tg acrylate emulsions with different glass transition temperature (Tg) values were prepared by adjusting the addition ratio of BA and MMA, and low Tg and high Tg silicon-acrylic emulsions were prepared by using γ-methacryloyloxypropyltrimethoxysilane (KH570) as cross-linked monomer modified acrylate emulsions. The compound emulsion was prepared by hard emulsion compounding, and finally the low-Tg, high-Tg silicon-acrylic emulsion and compound emulsion were used as water-based varnish binders to prepare water-based varnish. Based on SEM, TGA, DSC and tensile experiments, the effects of KH570 dosage (the mass percentage based on the total mass of polymeric monomer, the same below) on the properties of soft and hard silicon acrylic emulsions and water-based varnishes were investigated. The results showed that the average particle size of the low-Tg silicon-acrylic emulsion (dSiPA-3) prepared with KH570 dosage of 3% was 116.5 nm, the minimum film-forming temperature (MFT) was 16.6 °C, the water contact angle of the latex film was 68.6°, Tg=14.25 °C, the water resistance of water-based varnish was up to 50 times, the coating adhesion was grade 0, and the high temperature and anti-adhesion resistance could reach 150 °C. When dSiPA-3 is mixed with gSiPA-3 at the mass ratio of 0.8∶1, the MFT of the mixed emulsion is 33.8 ℃, the Tg of the latex film is 14.19 and 63.54 ℃, the water contact Angle is 77.9°, and the water-based gloss oil is resistant to friction for 500 times and water for 50 times. High temperature resistance and anti-adhesion temperature can reach 210 ℃, coating adhesion level 0.

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郑熙熙,费贵强,段仪豪,郑咏佳,王志东,白阳.水性光油用软硬硅丙复合乳液的制备及其耐高温性能影响[J].精细化工,2025,42(2):

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  • 收稿日期:2024-01-03
  • 最后修改日期:2024-03-06
  • 录用日期:2024-02-23
  • 在线发布日期: 2025-01-23
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